1-Phenyl-1H-pyrrole-2,5-dicarboxylic acid derivatives as versatile hydrogen-bonding motifs for the formation of one-, two- and three-dimensional networks in the solid state

Qing Lin, Steven J. Geib, Andrew D. Hamilton

Research output: Contribution to journalArticlepeer-review

Abstract

A series of 1-phenyl-1H-pyrrole-2,5-dicarboxylic acid derivatives were prepared and their solid state structures were investigated. Small structural changes in the monomeric subunit can lead to the formation of one-dimensional linear ribbons, two-dimensional sheets and three-dimensional networks. In each case a consistent feature of the solid state structures is the formation of bidentate hydrogen bonded contacts between the 2,5-carboxylic acid groups on adjacent pyrrole subunits. The exact nature of the crystal packing is strongly influenced by the substitution on the phenyl ring.

Original languageEnglish (US)
Pages (from-to)2109-2116
Number of pages8
JournalJournal of the Chemical Society. Perkin Transactions 2
Issue number10
DOIs
StatePublished - Oct 1998

ASJC Scopus subject areas

  • Chemistry(all)

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