1,5-Asymmetric induction during nucleophilic additions to arene-tricarbonyl-chromium complexes: Tricarbonyl(μ6-1-methyl-4- {spiro-[(1R,2S)-1,7,7-trimethyl-bicyclo-[2.2.1]heptane-3,2′-1,3-dioxolan] -2-yl-oxy}benzene)-chromium

Harinandini Paramahamsan; Anthony J. Pearson; Nathalie M. Pinkerton; A. Alan Pinkerton

doi:10.1107/S0108270108004666

1,5-Asymmetric induction during nucleophilic additions to arene-tricarbonyl-chromium complexes: Tricarbonyl(μ⁶-1-methyl-4- {spiro-[(1R,2S)-1,7,7-trimethyl-bicyclo-[2.2.1]heptane-3,2′-1,3-dioxolan] -2-yl-oxy}benzene)-chromium

Harinandini Paramahamsan, Anthony J. Pearson, Nathalie M. Pinkerton, A. Alan Pinkerton

Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

The tricarbonyl-chromium unit bound to the arene ring of the chiral title complex, [Cr(C19H26O3)(CO)3], is rotated by ca 25° in agreement with the proposed mechanism for 1,5-asymmetric induction of nucleophilic attack.

Original language	English (US)
Pages (from-to)	m147-m148
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	64
Issue number	4
DOIs	https://doi.org/10.1107/S0108270108004666
State	Published - Mar 15 2008

ASJC Scopus subject areas

General Biochemistry, Genetics and Molecular Biology

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Paramahamsan, H., Pearson, A. J., Pinkerton, N. M., & Pinkerton, A. A. (2008). 1,5-Asymmetric induction during nucleophilic additions to arene-tricarbonyl-chromium complexes: Tricarbonyl(μ⁶-1-methyl-4- {spiro-[(1R,2S)-1,7,7-trimethyl-bicyclo-[2.2.1]heptane-3,2′-1,3-dioxolan] -2-yl-oxy}benzene)-chromium. Acta Crystallographica Section C: Crystal Structure Communications, 64(4), m147-m148. https://doi.org/10.1107/S0108270108004666

1,5-Asymmetric induction during nucleophilic additions to arene-tricarbonyl-chromium complexes: Tricarbonyl(μ⁶-1-methyl-4- {spiro-[(1R,2S)-1,7,7-trimethyl-bicyclo-[2.2.1]heptane-3,2′-1,3-dioxolan] -2-yl-oxy}benzene)-chromium. / Paramahamsan, Harinandini; Pearson, Anthony J.; Pinkerton, Nathalie M. et al.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 64, No. 4, 15.03.2008, p. m147-m148.

Research output: Contribution to journal › Article › peer-review

Paramahamsan, H, Pearson, AJ, Pinkerton, NM & Pinkerton, AA 2008, '1,5-Asymmetric induction during nucleophilic additions to arene-tricarbonyl-chromium complexes: Tricarbonyl(μ⁶-1-methyl-4- {spiro-[(1R,2S)-1,7,7-trimethyl-bicyclo-[2.2.1]heptane-3,2′-1,3-dioxolan] -2-yl-oxy}benzene)-chromium', Acta Crystallographica Section C: Crystal Structure Communications, vol. 64, no. 4, pp. m147-m148. https://doi.org/10.1107/S0108270108004666

Paramahamsan H, Pearson AJ, Pinkerton NM, Pinkerton AA. 1,5-Asymmetric induction during nucleophilic additions to arene-tricarbonyl-chromium complexes: Tricarbonyl(μ⁶-1-methyl-4- {spiro-[(1R,2S)-1,7,7-trimethyl-bicyclo-[2.2.1]heptane-3,2′-1,3-dioxolan] -2-yl-oxy}benzene)-chromium. Acta Crystallographica Section C: Crystal Structure Communications. 2008 Mar 15;64(4):m147-m148. doi: 10.1107/S0108270108004666

Paramahamsan, Harinandini ; Pearson, Anthony J. ; Pinkerton, Nathalie M. et al. / 1,5-Asymmetric induction during nucleophilic additions to arene-tricarbonyl-chromium complexes : Tricarbonyl(μ⁶-1-methyl-4- {spiro-[(1R,2S)-1,7,7-trimethyl-bicyclo-[2.2.1]heptane-3,2′-1,3-dioxolan] -2-yl-oxy}benzene)-chromium. In: Acta Crystallographica Section C: Crystal Structure Communications. 2008 ; Vol. 64, No. 4. pp. m147-m148.

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