1,5-Asymmetric induction during nucleophilic additions to arene-tricarbonyl-chromium complexes: Tricarbonyl(μ6-1-methyl-4- {spiro-[(1R,2S)-1,7,7-trimethyl-bicyclo-[2.2.1]heptane-3,2′-1,3-dioxolan] -2-yl-oxy}benzene)-chromium

Harinandini Paramahamsan, Anthony J. Pearson, Nathalie M. Pinkerton, A. Alan Pinkerton

Research output: Contribution to journalArticlepeer-review

Abstract

The tricarbonyl-chromium unit bound to the arene ring of the chiral title complex, [Cr(C19H26O3)(CO)3], is rotated by ca 25° in agreement with the proposed mechanism for 1,5-asymmetric induction of nucleophilic attack.

Original languageEnglish (US)
Pages (from-to)m147-m148
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume64
Issue number4
DOIs
StatePublished - Mar 15 2008

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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