## Abstract

An improved version of the S-matrix Kohn variational method has been applied to calculating 3D quantum reaction probabilities of the ion-molecular reaction He + H^{+}_{2} (v → HeH^{+} + H. The calculation is carried out for total angular momentum J = 0 and employs the DIM potential surface of Kuntz. Our results show that vibrational excitation of H^{+}_{2} enhances the reaction probabilities and are in qualitative agreement with early experimental results. The calculated reaction probabilities are found to be highly oscillatory as a function of scattering energy and are associated with resonance of the system.

Original language | English (US) |
---|---|

Pages (from-to) | 489-495 |

Number of pages | 7 |

Journal | Chemical Physics Letters |

Volume | 173 |

Issue number | 5-6 |

DOIs | |

State | Published - Oct 19 1990 |

## ASJC Scopus subject areas

- Physics and Astronomy(all)
- Physical and Theoretical Chemistry

## Fingerprint

Dive into the research topics of '3D quantum scattering calculations of the reaction He + H^{+}

_{2}→ HeH

^{+}+ H for total angular momentum J = 0'. Together they form a unique fingerprint.