A formal synthesis of crinipellin B based on the arene-alkene meta- photocycloaddition reaction

Paul A. Wender; Timothy M. Dore

doi:10.1016/S0040-4039(98)01965-0

A formal synthesis of crinipellin B based on the arene-alkene meta- photocycloaddition reaction

Paul A. Wender, Timothy M. Dore

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Starting from triethyl phosphonopropionate and 3-nitro-2-methylbenzoic acid, a formal synthesis of crinipellin B was achieved. The strategy draws on the use of a novel version of the arene-alkene meta-photocycloaddition reaction that proceeds with the generation of 4 rings and 4 quaternary stereocenters in one synthetic operation.

Original language	English (US)
Pages (from-to)	8589-8592
Number of pages	4
Journal	Tetrahedron Letters
Volume	39
Issue number	47
DOIs	https://doi.org/10.1016/S0040-4039(98)01965-0
State	Published - Nov 19 1998

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(98)01965-0

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title = "A formal synthesis of crinipellin B based on the arene-alkene meta- photocycloaddition reaction",

abstract = "Starting from triethyl phosphonopropionate and 3-nitro-2-methylbenzoic acid, a formal synthesis of crinipellin B was achieved. The strategy draws on the use of a novel version of the arene-alkene meta-photocycloaddition reaction that proceeds with the generation of 4 rings and 4 quaternary stereocenters in one synthetic operation.",

author = "Wender, {Paul A.} and Dore, {Timothy M.}",

note = "Funding Information: Edward Piers for supplying the original spectral data from his intermediate, Ulrich Scholz for technical assistance, and the National Science Foundation for financial support.",

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doi = "10.1016/S0040-4039(98)01965-0",

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T1 - A formal synthesis of crinipellin B based on the arene-alkene meta- photocycloaddition reaction

AU - Wender, Paul A.

AU - Dore, Timothy M.

N1 - Funding Information: Edward Piers for supplying the original spectral data from his intermediate, Ulrich Scholz for technical assistance, and the National Science Foundation for financial support.

PY - 1998/11/19

Y1 - 1998/11/19

N2 - Starting from triethyl phosphonopropionate and 3-nitro-2-methylbenzoic acid, a formal synthesis of crinipellin B was achieved. The strategy draws on the use of a novel version of the arene-alkene meta-photocycloaddition reaction that proceeds with the generation of 4 rings and 4 quaternary stereocenters in one synthetic operation.

AB - Starting from triethyl phosphonopropionate and 3-nitro-2-methylbenzoic acid, a formal synthesis of crinipellin B was achieved. The strategy draws on the use of a novel version of the arene-alkene meta-photocycloaddition reaction that proceeds with the generation of 4 rings and 4 quaternary stereocenters in one synthetic operation.

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U2 - 10.1016/S0040-4039(98)01965-0

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 47

ER -

A formal synthesis of crinipellin B based on the arene-alkene meta- photocycloaddition reaction

Abstract

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