A macrocyclic supramolecular complex obtained from a fullerene ligand bearing two pyridine substituents and a bis-Zn(II)-porphyrin receptor

Fettah Ajamaa; Anne Marie Albrecht-Gary; Juan Luis Delgado De La Cruz; Mourad Elhabiri; Jean François Nierengarten; Nathalie Solladié; Ali Trabolsi; Maxence Urbani

doi:10.1142/S1088424606000715

A macrocyclic supramolecular complex obtained from a fullerene ligand bearing two pyridine substituents and a bis-Zn(II)-porphyrin receptor

Fettah Ajamaa, Anne Marie Albrecht-Gary, Juan Luis Delgado De La Cruz, Mourad Elhabiri, Jean François Nierengarten, Nathalie Solladié, Ali Trabolsi, Maxence Urbani

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A fullerene derivative bearing two pyridine subunits has been designed to allow assembly with a bis-Zn(II)-phorphyrin receptor with two equivalent Zn binding sites separated by about 20 Å. Owing to the complementarity between the bis-Zn(II)-porphyrin receptor and a fullerene ligand bearing two pyridine substituents, the substrate can be clicked on the ditopic receptor, thus leading to a stable non-covalent macrocyclic 1:1 complex.

Original language	English (US)
Pages (from-to)	1337-1345
Number of pages	9
Journal	Journal of Porphyrins and Phthalocyanines
Volume	10
Issue number	12
DOIs	https://doi.org/10.1142/S1088424606000715
State	Published - 2006

Keywords

Binding studies
Fullerene
Porphyrin
Supramolecular chemistry

ASJC Scopus subject areas

General Chemistry

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10.1142/S1088424606000715

Cite this

Ajamaa, F., Albrecht-Gary, A. M., De La Cruz, J. L. D., Elhabiri, M., Nierengarten, J. F., Solladié, N., Trabolsi, A., & Urbani, M. (2006). A macrocyclic supramolecular complex obtained from a fullerene ligand bearing two pyridine substituents and a bis-Zn(II)-porphyrin receptor. Journal of Porphyrins and Phthalocyanines, 10(12), 1337-1345. https://doi.org/10.1142/S1088424606000715

A macrocyclic supramolecular complex obtained from a fullerene ligand bearing two pyridine substituents and a bis-Zn(II)-porphyrin receptor. / Ajamaa, Fettah; Albrecht-Gary, Anne Marie; De La Cruz, Juan Luis Delgado et al.
In: Journal of Porphyrins and Phthalocyanines, Vol. 10, No. 12, 2006, p. 1337-1345.

Research output: Contribution to journal › Article › peer-review

Ajamaa, F, Albrecht-Gary, AM, De La Cruz, JLD, Elhabiri, M, Nierengarten, JF, Solladié, N, Trabolsi, A & Urbani, M 2006, 'A macrocyclic supramolecular complex obtained from a fullerene ligand bearing two pyridine substituents and a bis-Zn(II)-porphyrin receptor', Journal of Porphyrins and Phthalocyanines, vol. 10, no. 12, pp. 1337-1345. https://doi.org/10.1142/S1088424606000715

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title = "A macrocyclic supramolecular complex obtained from a fullerene ligand bearing two pyridine substituents and a bis-Zn(II)-porphyrin receptor",

abstract = "A fullerene derivative bearing two pyridine subunits has been designed to allow assembly with a bis-Zn(II)-phorphyrin receptor with two equivalent Zn binding sites separated by about 20 {\AA}. Owing to the complementarity between the bis-Zn(II)-porphyrin receptor and a fullerene ligand bearing two pyridine substituents, the substrate can be clicked on the ditopic receptor, thus leading to a stable non-covalent macrocyclic 1:1 complex.",

keywords = "Binding studies, Fullerene, Porphyrin, Supramolecular chemistry",

author = "Fettah Ajamaa and Albrecht-Gary, {Anne Marie} and {De La Cruz}, {Juan Luis Delgado} and Mourad Elhabiri and Nierengarten, {Jean Fran{\c c}ois} and Nathalie Solladi{\'e} and Ali Trabolsi and Maxence Urbani",

note = "Funding Information: This work was supported by the CNRS (UMR 7509 and UPR 8241) and the French Ministry of Research (ACI Jeunes Chercheurs to N.S., doctoral fellowships to A. T. and M. U.).",

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doi = "10.1142/S1088424606000715",

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AU - Ajamaa, Fettah

AU - Albrecht-Gary, Anne Marie

AU - De La Cruz, Juan Luis Delgado

AU - Elhabiri, Mourad

AU - Nierengarten, Jean François

AU - Solladié, Nathalie

AU - Trabolsi, Ali

AU - Urbani, Maxence

N1 - Funding Information: This work was supported by the CNRS (UMR 7509 and UPR 8241) and the French Ministry of Research (ACI Jeunes Chercheurs to N.S., doctoral fellowships to A. T. and M. U.).

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AB - A fullerene derivative bearing two pyridine subunits has been designed to allow assembly with a bis-Zn(II)-phorphyrin receptor with two equivalent Zn binding sites separated by about 20 Å. Owing to the complementarity between the bis-Zn(II)-porphyrin receptor and a fullerene ligand bearing two pyridine substituents, the substrate can be clicked on the ditopic receptor, thus leading to a stable non-covalent macrocyclic 1:1 complex.

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KW - Fullerene

KW - Porphyrin

KW - Supramolecular chemistry

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A macrocyclic supramolecular complex obtained from a fullerene ligand bearing two pyridine substituents and a bis-Zn(II)-porphyrin receptor

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Keywords

ASJC Scopus subject areas

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