TY - JOUR
T1 - A one-step synthesis of azide-tagged carbohydrates
T2 - Versatile intermediates for glycotechnology
AU - Sanki, Aditya K.
AU - Mahal, Lara K.
PY - 2006/2/15
Y1 - 2006/2/15
N2 - Herein we describe a simple and practical methodology for accessing both the α-anomers (D-mannose, N-acetyl-D-glucosamine, N-acetyl-D- galactosamine, D-lactose) and α- and β-anomers (D-glucose, D-galactose, L-fucose) of 2′-azidoethyl and azidotriethylene glycol glycosides using free sugars and Dowex 50 (resin) as an efficient catalyst. These azidoalkyl glycosides are increasingly useful synthetic intermediates for glycotechnology.
AB - Herein we describe a simple and practical methodology for accessing both the α-anomers (D-mannose, N-acetyl-D-glucosamine, N-acetyl-D- galactosamine, D-lactose) and α- and β-anomers (D-glucose, D-galactose, L-fucose) of 2′-azidoethyl and azidotriethylene glycol glycosides using free sugars and Dowex 50 (resin) as an efficient catalyst. These azidoalkyl glycosides are increasingly useful synthetic intermediates for glycotechnology.
KW - Azidoethyl glycosides
KW - Azidotriethylene glycol glycosides
KW - Glycotechnology
KW - Resin-catalyzed glycosylation
UR - http://www.scopus.com/inward/record.url?scp=33344465143&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33344465143&partnerID=8YFLogxK
U2 - 10.1055/s-2006-926264
DO - 10.1055/s-2006-926264
M3 - Article
AN - SCOPUS:33344465143
SN - 0936-5214
SP - 455
EP - 459
JO - Synlett
JF - Synlett
IS - 3
ER -