A reasonable accounting for mass spectral stereoisomeric effects in substituted cyclohexanols

Mark M. Green; Richard J. Cook; W. Rayle; E. Walton; Marvin F. Grostic

doi:10.1039/C29690000081

A reasonable accounting for mass spectral stereoisomeric effects in substituted cyclohexanols

Mark M. Green, Richard J. Cook, W. Rayle, E. Walton, Marvin F. Grostic

Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

Original language	English (US)
Pages (from-to)	81-82
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/C29690000081
State	Published - 1969

ASJC Scopus subject areas

Molecular Medicine

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@article{4ef9e1ba9a324298b4edc6303fdd990a,

title = "A reasonable accounting for mass spectral stereoisomeric effects in substituted cyclohexanols",

author = "Green, {Mark M.} and Cook, {Richard J.} and W. Rayle and E. Walton and Grostic, {Marvin F.}",

note = "Funding Information: Nevertheless this work, and the work of others192.6 indicates that a non-empirical approach may fulfil the expected? potential of mass spectrometry for stereo- chemical studies in these, and related alicyclic molecules. We thank the Petroleum Research Fund of the American Chemical Society for financial support and Research Corporation for a Frederic Gardner Cottrell grant. R.J .C. and E.W. are indebted to the N.S.F. for undergraduate summer stipends. (Received, October 7th, 1968; Corn. 1365.) 1 C. E. Brion and L. D. Hall, J. Amer. Chem. Soc., 1966,238, 3661. 2 L. DolejS and V. HanuS, Coll. Czech. Chem. Comm., 1968, 33, 332. 9 H. Budzikiewicz, 2. Pelah, and C. Djerassi, Monatsh. Chem., 1964, 95, 158; M. M. Green and J. Schwab, Tetrahedron Letters, 1968, 2955. 4 The 1,4 is favoured over the 1{\textquoteright}3 mode of elimination in both alicyclic and cyclic alcohols; see: W. Benz and K. Biemann, J. Amer. Chem. Soc., 1964, 86, 2375; S. Meyerson and L. C. Leitch, ibid., 1964,86, 2555 and ref. 3. 5 E. L. Eliel, N. L. Allinger, S. J. Angyal, and G. A. Morrison, “Conformational Analysis,” Interscience, New York, 1965, pp. 115-116 and 177-178 and references therein. 6 C. G. MacDonald, J. S. Shannon and G. Sugowdz, Tetrahedron Letters, 1963, 807. 7 See ref. 5, pp. 187-188.",

year = "1969",

doi = "10.1039/C29690000081",

language = "English (US)",

pages = "81--82",

journal = "Journal of the Chemical Society D: Chemical Communications",

issn = "0577-6171",

publisher = "Royal Society of Chemistry",

number = "3",

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TY - JOUR

T1 - A reasonable accounting for mass spectral stereoisomeric effects in substituted cyclohexanols

AU - Green, Mark M.

AU - Cook, Richard J.

AU - Rayle, W.

AU - Walton, E.

AU - Grostic, Marvin F.

N1 - Funding Information: Nevertheless this work, and the work of others192.6 indicates that a non-empirical approach may fulfil the expected? potential of mass spectrometry for stereo- chemical studies in these, and related alicyclic molecules. We thank the Petroleum Research Fund of the American Chemical Society for financial support and Research Corporation for a Frederic Gardner Cottrell grant. R.J .C. and E.W. are indebted to the N.S.F. for undergraduate summer stipends. (Received, October 7th, 1968; Corn. 1365.) 1 C. E. Brion and L. D. Hall, J. Amer. Chem. Soc., 1966,238, 3661. 2 L. DolejS and V. HanuS, Coll. Czech. Chem. Comm., 1968, 33, 332. 9 H. Budzikiewicz, 2. Pelah, and C. Djerassi, Monatsh. Chem., 1964, 95, 158; M. M. Green and J. Schwab, Tetrahedron Letters, 1968, 2955. 4 The 1,4 is favoured over the 1’3 mode of elimination in both alicyclic and cyclic alcohols; see: W. Benz and K. Biemann, J. Amer. Chem. Soc., 1964, 86, 2375; S. Meyerson and L. C. Leitch, ibid., 1964,86, 2555 and ref. 3. 5 E. L. Eliel, N. L. Allinger, S. J. Angyal, and G. A. Morrison, “Conformational Analysis,” Interscience, New York, 1965, pp. 115-116 and 177-178 and references therein. 6 C. G. MacDonald, J. S. Shannon and G. Sugowdz, Tetrahedron Letters, 1963, 807. 7 See ref. 5, pp. 187-188.

PY - 1969

Y1 - 1969

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JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

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ER -

A reasonable accounting for mass spectral stereoisomeric effects in substituted cyclohexanols

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