A review on the potential of cellulose nanomaterials for the development of thin film composite polyamide membranes for water treatment

Membrane-based separation technologies have drawn significant interest because of their compactness, low energy consumption, and ability to be easily integrated with existing processes. There has been significant interest in the utilization of natural materials derived from sustainable and renewable resources for membrane fabrication. Cellulose is one of the promising polymers which has been extensively studied in membrane fabrication and modification due to its abundant availability, non-toxicity and biodegradability. While there have been several reviews in recent years separately on TFC membranes and cellulose-based materials for different applications, reviews exclusively focusing on cellulosic nanomaterials-based TFC membranes are still lacking. This review provides an overview of the types of cellulose nanomaterials exploited for the development and modification of TFC membranes, particularly those used for desalination and wastewater treatment. We have presented a brief description of cellulose-based nanomaterials followed by a detailed discussion of different studies addressing each cellulose nanomaterial separately. In addition, we have summarized the performance of different studies in the literature, paying particular attention to the enhancement achieved by the incorporation of cellulose nanomaterial in the membrane.