A stable tetraalkyl complex of nickel(IV)

Matthew Carnes; Daniela Buccella; Judy Y.C. Chen; Arthur P. Ramirez; Nicholas J. Turro; Colin Nuckolls; Michael Steigerwald

doi:10.1002/anie.200804435

A stable tetraalkyl complex of nickel(IV)

Matthew Carnes, Daniela Buccella, Judy Y.C. Chen, Arthur P. Ramirez, Nicholas J. Turro, Colin Nuckolls, Michael Steigerwald

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Ni takes a load off: Nickel(0) and a strained alkene react to form a stable tris(alkene) complex, which eliminates the corresponding trans,trans,trans- cyclobutane upon heating. A higher proportion of alkene to Ni⁰ precursor yielded the first all-alkyl complex of nickel(IV) (see structure; Ni: green). These reactions, which involve ligand coupling, are driven by relief of ring strain in the alkene. (Figure Presented).

Original language	English (US)
Pages (from-to)	290-294
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	2
DOIs	https://doi.org/10.1002/anie.200804435
State	Published - Jan 2 2009

Keywords

Alkene ligands
Cycloaddition
Nickel
Organometallic compounds

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200804435

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AU - Nuckolls, Colin

AU - Steigerwald, Michael

PY - 2009/1/2

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AB - Ni takes a load off: Nickel(0) and a strained alkene react to form a stable tris(alkene) complex, which eliminates the corresponding trans,trans,trans- cyclobutane upon heating. A higher proportion of alkene to Ni0 precursor yielded the first all-alkyl complex of nickel(IV) (see structure; Ni: green). These reactions, which involve ligand coupling, are driven by relief of ring strain in the alkene. (Figure Presented).

KW - Alkene ligands

KW - Cycloaddition

KW - Nickel

KW - Organometallic compounds

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A stable tetraalkyl complex of nickel(IV)

Abstract

Keywords

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