Absolute Configuration and Optical Rotatory Power of Sulfoxides and Sulfinate Esters1, 2

Kurt Mislow; Mark M. Green; Peter Laur; Joseph T. Melillo; Todd Simmons; Andrew L. Ternay

doi:10.1021/ja01087a020

Absolute Configuration and Optical Rotatory Power of Sulfoxides and Sulfinate Esters1, 2

Kurt Mislow, Mark M. Green, Peter Laur, Joseph T. Melillo, Todd Simmons, Andrew L. Ternay

Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Evidence is presented which firmly establishes the absolute configuration of a number of sulfinate esters and sulfoxides. Previous speculations which bear on the problem of the absolute configuration of optically active sulfoxides and sulfinate esters are critically examined. The optical rotatory dispersion of sulfoxides and sulfinate esters has been investigated. The observed Cotton effects are for the most part conveniently categorized according to the previously adopted viewpoint of inherently dissymmetric and asymmetrically perturbed symmetric chromophores.

Original language	English (US)
Pages (from-to)	1958-1976
Number of pages	19
Journal	Journal of the American Chemical Society
Volume	87
Issue number	9
DOIs	https://doi.org/10.1021/ja01087a020
State	Published - 1965

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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abstract = "Evidence is presented which firmly establishes the absolute configuration of a number of sulfinate esters and sulfoxides. Previous speculations which bear on the problem of the absolute configuration of optically active sulfoxides and sulfinate esters are critically examined. The optical rotatory dispersion of sulfoxides and sulfinate esters has been investigated. The observed Cotton effects are for the most part conveniently categorized according to the previously adopted viewpoint of inherently dissymmetric and asymmetrically perturbed symmetric chromophores.",

author = "Kurt Mislow and Green, {Mark M.} and Peter Laur and Melillo, {Joseph T.} and Todd Simmons and Ternay, {Andrew L.}",

year = "1965",

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AU - Mislow, Kurt

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AU - Laur, Peter

AU - Melillo, Joseph T.

AU - Simmons, Todd

AU - Ternay, Andrew L.

PY - 1965

Y1 - 1965

N2 - Evidence is presented which firmly establishes the absolute configuration of a number of sulfinate esters and sulfoxides. Previous speculations which bear on the problem of the absolute configuration of optically active sulfoxides and sulfinate esters are critically examined. The optical rotatory dispersion of sulfoxides and sulfinate esters has been investigated. The observed Cotton effects are for the most part conveniently categorized according to the previously adopted viewpoint of inherently dissymmetric and asymmetrically perturbed symmetric chromophores.

AB - Evidence is presented which firmly establishes the absolute configuration of a number of sulfinate esters and sulfoxides. Previous speculations which bear on the problem of the absolute configuration of optically active sulfoxides and sulfinate esters are critically examined. The optical rotatory dispersion of sulfoxides and sulfinate esters has been investigated. The observed Cotton effects are for the most part conveniently categorized according to the previously adopted viewpoint of inherently dissymmetric and asymmetrically perturbed symmetric chromophores.

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Absolute Configuration and Optical Rotatory Power of Sulfoxides and Sulfinate Esters1, 2

Abstract

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