Benzhydryldimethylsilyl allylic silanes: Syntheses and applications to [3 + 2] annulation reactions

Zhi Hui Peng, K. A. Woerpel

Research output: Contribution to journalArticlepeer-review

Abstract

(Matrix Presented) A new silyl group, the benzhydryldimethylsilyl group, has been developed that is easily synthesized and that undergoes facile oxidation. The [3 + 2] annulation reactions of allylic silanes with this silyl group provide a variety of highly substituted five-membered carbocycles and heterocycles with high stereoselectivities. The silyl groups of these cyclic compounds have been oxidized to hydroxyl groups to demonstrate the general synthetic utility of the method.

Original languageEnglish (US)
Pages (from-to)1379-1381
Number of pages3
JournalOrganic Letters
Volume2
Issue number10
DOIs
StatePublished - May 18 2000

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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