Bhc-diol as a photolabile protecting group for aldehydes and ketones

Min Lu; Olesya D. Fedoryak; Brent R. Moister; Timothy M. Dore

doi:10.1021/ol034536b

Bhc-diol as a photolabile protecting group for aldehydes and ketones

Min Lu, Olesya D. Fedoryak, Brent R. Moister, Timothy M. Dore

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

(Matrix presented) 6-Bromo-4-(1,2-dihydroxyethyl)-7-hydroxycoumarin (Bhc-diol) can be used under simulated physiological conditions as a photoremovable protecting group for aldehydes and ketones. The single- and two-photon-induced release of benzaldehyde, piperonal, acetophenone, and cyclohexanone is demonstrated.

Original language	English (US)
Pages (from-to)	2119-2122
Number of pages	4
Journal	Organic Letters
Volume	5
Issue number	12
DOIs	https://doi.org/10.1021/ol034536b
State	Published - Jun 12 2003

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol034536b

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title = "Bhc-diol as a photolabile protecting group for aldehydes and ketones",

abstract = "(Matrix presented) 6-Bromo-4-(1,2-dihydroxyethyl)-7-hydroxycoumarin (Bhc-diol) can be used under simulated physiological conditions as a photoremovable protecting group for aldehydes and ketones. The single- and two-photon-induced release of benzaldehyde, piperonal, acetophenone, and cyclohexanone is demonstrated.",

author = "Min Lu and Fedoryak, {Olesya D.} and Moister, {Brent R.} and Dore, {Timothy M.}",

year = "2003",

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AU - Lu, Min

AU - Fedoryak, Olesya D.

AU - Moister, Brent R.

AU - Dore, Timothy M.

PY - 2003/6/12

Y1 - 2003/6/12

N2 - (Matrix presented) 6-Bromo-4-(1,2-dihydroxyethyl)-7-hydroxycoumarin (Bhc-diol) can be used under simulated physiological conditions as a photoremovable protecting group for aldehydes and ketones. The single- and two-photon-induced release of benzaldehyde, piperonal, acetophenone, and cyclohexanone is demonstrated.

AB - (Matrix presented) 6-Bromo-4-(1,2-dihydroxyethyl)-7-hydroxycoumarin (Bhc-diol) can be used under simulated physiological conditions as a photoremovable protecting group for aldehydes and ketones. The single- and two-photon-induced release of benzaldehyde, piperonal, acetophenone, and cyclohexanone is demonstrated.

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JO - Organic Letters

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Bhc-diol as a photolabile protecting group for aldehydes and ketones

Abstract

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