Broad band dipolar recoupling in the nuclear magnetic resonance of rotating solids

D. K. Sodickson; M. H. Levitt; S. Vega; R. G. Griffin

doi:10.1063/1.464766

Broad band dipolar recoupling in the nuclear magnetic resonance of rotating solids

D. K. Sodickson, M. H. Levitt, S. Vega, R. G. Griffin

Biomedical Engineering

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Abstract

The effects of homonuclear dipole couplings may be reintroduced into magic angle spinning nuclear magnetic resonance (NMR) spectra by judiciously spaced π pulse trains. This recoupling phenomenon occurs over a wide range of chemical shift differences and sample rotation speeds. We present results of magnetization exchange experiments exploiting the broad band recoupling effect, and propose a theoretical description in which pulse-assisted dipolar recoupling may be understood as a form of compensated rotational resonance.

Original language	English (US)
Pages (from-to)	6742-6748
Number of pages	7
Journal	The Journal of Chemical Physics
Volume	98
Issue number	9
DOIs	https://doi.org/10.1063/1.464766
State	Published - 1993

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1063/1.464766

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abstract = "The effects of homonuclear dipole couplings may be reintroduced into magic angle spinning nuclear magnetic resonance (NMR) spectra by judiciously spaced π pulse trains. This recoupling phenomenon occurs over a wide range of chemical shift differences and sample rotation speeds. We present results of magnetization exchange experiments exploiting the broad band recoupling effect, and propose a theoretical description in which pulse-assisted dipolar recoupling may be understood as a form of compensated rotational resonance.",

author = "Sodickson, {D. K.} and Levitt, {M. H.} and S. Vega and Griffin, {R. G.}",

year = "1993",

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AU - Sodickson, D. K.

AU - Levitt, M. H.

AU - Vega, S.

AU - Griffin, R. G.

PY - 1993

Y1 - 1993

N2 - The effects of homonuclear dipole couplings may be reintroduced into magic angle spinning nuclear magnetic resonance (NMR) spectra by judiciously spaced π pulse trains. This recoupling phenomenon occurs over a wide range of chemical shift differences and sample rotation speeds. We present results of magnetization exchange experiments exploiting the broad band recoupling effect, and propose a theoretical description in which pulse-assisted dipolar recoupling may be understood as a form of compensated rotational resonance.

AB - The effects of homonuclear dipole couplings may be reintroduced into magic angle spinning nuclear magnetic resonance (NMR) spectra by judiciously spaced π pulse trains. This recoupling phenomenon occurs over a wide range of chemical shift differences and sample rotation speeds. We present results of magnetization exchange experiments exploiting the broad band recoupling effect, and propose a theoretical description in which pulse-assisted dipolar recoupling may be understood as a form of compensated rotational resonance.

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Broad band dipolar recoupling in the nuclear magnetic resonance of rotating solids

Abstract

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