Calculated absolute electron impact ionization cross-section for the molecules CF3X (X = H, Br, I)

U. Onthong; H. Deutsch; K. Becker; S. Matt; M. Probst; T. D. Märk

doi:10.1016/S1387-3806(01)00556-5

Calculated absolute electron impact ionization cross-section for the molecules CF₃X (X = H, Br, I)

U. Onthong, H. Deutsch, K. Becker, S. Matt, M. Probst, T. D. Märk

Research output: Contribution to journal › Article › peer-review

Abstract

We report calculated total single ionization cross-sections for the three molecules - CFH₃, CF₃Br, and CF₃I using the Deutsch-Märk (DM) formalism. In the case of CF₃H, our calculated cross-sections are in good agreement with the BEB calculation of Kim et al. and with the recent measurement of Iga et al., but disagree with earlier experimental data. Our calculated cross-sections for CF₃Br and CF₃I are in good agreement with recent experiments, which reported measured data for these two molecules for the first time.

Original language	English (US)
Pages (from-to)	53-56
Number of pages	4
Journal	International Journal of Mass Spectrometry
Volume	214
Issue number	1
DOIs	https://doi.org/10.1016/S1387-3806(01)00556-5
State	Published - Feb 15 2002

Keywords

Cross-sections
Electron impact ionization
Ion chemistry

ASJC Scopus subject areas

Instrumentation
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry

Access to Document

10.1016/S1387-3806(01)00556-5

Cite this

@article{97c0a824f5f941d48b2e5e0ceda19a45,

title = "Calculated absolute electron impact ionization cross-section for the molecules CF3X (X = H, Br, I)",

abstract = "We report calculated total single ionization cross-sections for the three molecules - CFH3, CF3Br, and CF3I using the Deutsch-M{\"a}rk (DM) formalism. In the case of CF3H, our calculated cross-sections are in good agreement with the BEB calculation of Kim et al. and with the recent measurement of Iga et al., but disagree with earlier experimental data. Our calculated cross-sections for CF3Br and CF3I are in good agreement with recent experiments, which reported measured data for these two molecules for the first time.",

keywords = "Cross-sections, Electron impact ionization, Ion chemistry",

author = "U. Onthong and H. Deutsch and K. Becker and S. Matt and M. Probst and M{\"a}rk, {T. D.}",

note = "Funding Information: This work was partially supported by the {\"O}sterreichischer Fonds zur F{\"o}rderung der Wissenschaftlichen Forschung, Wien, Austria and the EU Commission through the Human Potential Network programme, Brussels. One of us (K.B.) wishes to acknowledge partial financial support from the Division of Chemical Sciences, Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy.",

year = "2002",

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TY - JOUR

T1 - Calculated absolute electron impact ionization cross-section for the molecules CF3X (X = H, Br, I)

AU - Onthong, U.

AU - Deutsch, H.

AU - Becker, K.

AU - Matt, S.

AU - Probst, M.

AU - Märk, T. D.

N1 - Funding Information: This work was partially supported by the Österreichischer Fonds zur Förderung der Wissenschaftlichen Forschung, Wien, Austria and the EU Commission through the Human Potential Network programme, Brussels. One of us (K.B.) wishes to acknowledge partial financial support from the Division of Chemical Sciences, Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy.

PY - 2002/2/15

Y1 - 2002/2/15

N2 - We report calculated total single ionization cross-sections for the three molecules - CFH3, CF3Br, and CF3I using the Deutsch-Märk (DM) formalism. In the case of CF3H, our calculated cross-sections are in good agreement with the BEB calculation of Kim et al. and with the recent measurement of Iga et al., but disagree with earlier experimental data. Our calculated cross-sections for CF3Br and CF3I are in good agreement with recent experiments, which reported measured data for these two molecules for the first time.

AB - We report calculated total single ionization cross-sections for the three molecules - CFH3, CF3Br, and CF3I using the Deutsch-Märk (DM) formalism. In the case of CF3H, our calculated cross-sections are in good agreement with the BEB calculation of Kim et al. and with the recent measurement of Iga et al., but disagree with earlier experimental data. Our calculated cross-sections for CF3Br and CF3I are in good agreement with recent experiments, which reported measured data for these two molecules for the first time.

KW - Cross-sections

KW - Electron impact ionization

KW - Ion chemistry

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U2 - 10.1016/S1387-3806(01)00556-5

DO - 10.1016/S1387-3806(01)00556-5

M3 - Article

AN - SCOPUS:0037083691

SN - 1387-3806

VL - 214

SP - 53

EP - 56

JO - International Journal of Mass Spectrometry

JF - International Journal of Mass Spectrometry

IS - 1

ER -