Characterization of natural pozzolan-based geopolymeric binders

Juhyuk Moon, Sungchul Bae, Kemal Celik, Seyoon Yoon, Ki Hyun Kim, Kang Su Kim, Paulo J.M. Monteiro

Research output: Contribution to journalArticle

Abstract

Properties and characteristics of fly ash- or slag-based geopolymers have been extensively explored but comparatively less information is available for natural pozzolan-based geopolymers. The present work focuses on microstructural characteristics of natural pozzolan-based geopolymers activated by sodium hydroxide and a mixture of sodium hydroxide and sodium silicate. Synchrotron XRD and SEM-EDS studies combined with compressive strength tests successfully demonstrate the feasibility of the use of natural pozzolan for sustainable construction material. It is concluded that the geopolymers have sufficient strength as structural materials and matrices contain C-S-H like crystal as well as zeolites of hydroxysodalite and zeolite Y. Two zeolites of hydroxysodalite and zeolite Y are found as the main activation products in sodium hydroxide activation. Substitution with sodium silicate solution yields higher compressive strength and a denser microstructure with dominant activation products of C-S-H like crystal, zeolite Y, and phillipsite. It has been proposed that the crystal size of the activation products ranges from 10 nm to 1 μm. Different microstructural characteristics found herein provide a valuable information to develop natural pozzolan-based sustainable structural materials with improved properties.

Original languageEnglish (US)
Pages (from-to)97-104
Number of pages8
JournalCement and Concrete Composites
Volume53
DOIs
StatePublished - Oct 2014

Keywords

  • Basaltic ash
  • Compressive strength
  • Geopolymer
  • Natural pozzolan

ASJC Scopus subject areas

  • Building and Construction
  • Materials Science(all)

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