@article{87ebec85766641c283548ba35c6e2985,
title = "Chemiluminescence-promoted oxidation of alkyl enol ethers by NHPI under mild conditions and in the dark",
abstract = "The hydroperoxidation of alkyl enol ethers using N-hydroxyphthalimide and molecular oxygen occurred in the absence of catalyst, initiator, or light. The reaction proceeds through a radical mechanism that is initiated by N-hydroxyphthalimide-promoted autoxidation of the enol ether substrate. The resulting dioxetane products decompose in a chemiluminescent reaction that allows for photochemical activation of N-hydroxyphthalimide in the absence of other light sources.",
keywords = "Autoxidation, Chemiluminescence, Dark, Enol ether, NHPI, Oxidation, Radical",
author = "Anderson, {T. E.} and Andia, {Alexander A.} and Woerpel, {K. A.}",
note = "Funding Information: This research was supported by the National Institute of General Medical Sciences of the National Institutes of Health ( 1R01GM118730 ). NMR spectra acquired with the Bruker Avance 400 and 500 NMR spectrometers were supported by the National Science Foundation ( CHE-01162222 ). The authors thank Dr. Chin Lin (NYU) for his assistance with NMR spectroscopy and mass spectrometry, as well as the NYU Genomics Core Facility for use of their Tecan Spark Microplate Reader. Publisher Copyright: {\textcopyright} 2020 Elsevier Ltd Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = feb,
day = "26",
doi = "10.1016/j.tet.2020.131874",
language = "English (US)",
volume = "82",
journal = "Tetrahedron",
issn = "0040-4020",
publisher = "Elsevier Limited",
}