Chiroptical Sensors

J. W. Canary; X. Duan; X. Liu

doi:10.1016/B978-0-12-409547-2.12091-8

Chiroptical Sensors

J. W. Canary, X. Duan, X. Liu

Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter

Abstract

Chiroptical sensors play a very important role in detecting a wide range of analytes with a high level of sensitivity, responding not only to complexation-induced electronic effects but also changes in helicity and conformation of molecules and materials. Many scaffolds have been employed that respond to metal cations, small molecules, anions, and other analytes. This article describes the main scheme of chiroptical sensing and introduces various chiroptical sensors that are primarily based on circular dichroism spectroscopy. Several examples are highlighted to illustrate the progress in recent years.

Original language	English (US)
Title of host publication	Encyclopedia of Spectroscopy and Spectrometry
Publisher	Elsevier Inc.
Pages	203-210
Number of pages	8
ISBN (Print)	9780128032244
DOIs	https://doi.org/10.1016/B978-0-12-409547-2.12091-8
State	Published - 2017

Keywords

Absolute configuration
Anion
Chiral analyte
Chirality
Chiroptical sensor
Circularly dichroism
Enantiomeric excess
Fluorescent sensing
Metal ion
Spectroscopy

ASJC Scopus subject areas

Instrumentation
Atomic and Molecular Physics, and Optics
Spectroscopy

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10.1016/B978-0-12-409547-2.12091-8

Cite this

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abstract = "Chiroptical sensors play a very important role in detecting a wide range of analytes with a high level of sensitivity, responding not only to complexation-induced electronic effects but also changes in helicity and conformation of molecules and materials. Many scaffolds have been employed that respond to metal cations, small molecules, anions, and other analytes. This article describes the main scheme of chiroptical sensing and introduces various chiroptical sensors that are primarily based on circular dichroism spectroscopy. Several examples are highlighted to illustrate the progress in recent years.",

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T1 - Chiroptical Sensors

AU - Canary, J. W.

AU - Duan, X.

AU - Liu, X.

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AB - Chiroptical sensors play a very important role in detecting a wide range of analytes with a high level of sensitivity, responding not only to complexation-induced electronic effects but also changes in helicity and conformation of molecules and materials. Many scaffolds have been employed that respond to metal cations, small molecules, anions, and other analytes. This article describes the main scheme of chiroptical sensing and introduces various chiroptical sensors that are primarily based on circular dichroism spectroscopy. Several examples are highlighted to illustrate the progress in recent years.

KW - Absolute configuration

KW - Anion

KW - Chiral analyte

KW - Chirality

KW - Chiroptical sensor

KW - Circularly dichroism

KW - Enantiomeric excess

KW - Fluorescent sensing

KW - Metal ion

KW - Spectroscopy

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M3 - Chapter

AN - SCOPUS:85060139068

SN - 9780128032244

SP - 203

EP - 210

BT - Encyclopedia of Spectroscopy and Spectrometry

PB - Elsevier Inc.

ER -

Chiroptical Sensors

Abstract

Keywords

ASJC Scopus subject areas

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