Cobalt-Catalyzed Intramolecular Silylperoxidation of Unsaturated Diisopropylsilyl Ethers

Jonathan P. Oswald; K. A. Woerpel

doi:10.1021/acs.joc.9b00642

Cobalt-Catalyzed Intramolecular Silylperoxidation of Unsaturated Diisopropylsilyl Ethers

Jonathan P. Oswald, K. A. Woerpel

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A cobalt-catalyzed intramolecular silylperoxidation reaction was developed that allows for the conversion of unsaturated diisopropylsilyl ethers to 3-sila-1,2,4-trioxepanes. Reduction of the peroxide unit of the 3-sila-1,2,4-trioxepane yields six-membered ring diisopropylsilylene acetals.

Original language	English (US)
Pages (from-to)	7564-7574
Number of pages	11
Journal	Journal of Organic Chemistry
Volume	84
Issue number	12
DOIs	https://doi.org/10.1021/acs.joc.9b00642
State	Published - Jun 21 2019

ASJC Scopus subject areas

Organic Chemistry

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title = "Cobalt-Catalyzed Intramolecular Silylperoxidation of Unsaturated Diisopropylsilyl Ethers",

abstract = "A cobalt-catalyzed intramolecular silylperoxidation reaction was developed that allows for the conversion of unsaturated diisopropylsilyl ethers to 3-sila-1,2,4-trioxepanes. Reduction of the peroxide unit of the 3-sila-1,2,4-trioxepane yields six-membered ring diisopropylsilylene acetals.",

author = "Oswald, {Jonathan P.} and Woerpel, {K. A.}",

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