@article{e0182f0cc72c4cdbb488330652c32241,
title = "Cobalt-Catalyzed Intramolecular Silylperoxidation of Unsaturated Diisopropylsilyl Ethers",
abstract = "A cobalt-catalyzed intramolecular silylperoxidation reaction was developed that allows for the conversion of unsaturated diisopropylsilyl ethers to 3-sila-1,2,4-trioxepanes. Reduction of the peroxide unit of the 3-sila-1,2,4-trioxepane yields six-membered ring diisopropylsilylene acetals.",
author = "Oswald, {Jonathan P.} and Woerpel, {K. A.}",
note = "Funding Information: This research was supported by the National Institute of General Medical Sciences of the National Institutes of Health (1R01GM118730). NMR spectra acquired with the TCI cryoprobe and Bruker Avance 400 spectrometer were supported by the National Institutes of Health (OD016343) and the National Science Foundation (CHE-01162222), respectively. The authors thank Dr. Chin Lin for his assistance with NMR spectroscopy and mass spectrometry. Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",
year = "2019",
month = jun,
day = "21",
doi = "10.1021/acs.joc.9b00642",
language = "English (US)",
volume = "84",
pages = "7564--7574",
journal = "Journal of Organic Chemistry",
issn = "0022-3263",
publisher = "American Chemical Society",
number = "12",
}