Abstract
A cobalt-catalyzed intramolecular silylperoxidation reaction was developed that allows for the conversion of unsaturated diisopropylsilyl ethers to 3-sila-1,2,4-trioxepanes. Reduction of the peroxide unit of the 3-sila-1,2,4-trioxepane yields six-membered ring diisopropylsilylene acetals.
Original language | English (US) |
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Pages (from-to) | 7564-7574 |
Number of pages | 11 |
Journal | Journal of Organic Chemistry |
Volume | 84 |
Issue number | 12 |
DOIs | |
State | Published - Jun 21 2019 |
ASJC Scopus subject areas
- Organic Chemistry