Colloidal diamond

Mingxin He, Johnathon P. Gales, Étienne Ducrot, Zhe Gong, Gi Ra Yi, Stefano Sacanna, David J. Pine

Research output: Contribution to journalArticle

Abstract

Self-assembling colloidal particles in the cubic diamond crystal structure could potentially be used to make materials with a photonic bandgap1–3. Such materials are beneficial because they suppress spontaneous emission of light1 and are valued for their applications as optical waveguides, filters and laser resonators4, for improving light-harvesting technologies5–7 and for other applications4,8. Cubic diamond is preferred for these applications over more easily self-assembled structures, such as face-centred-cubic structures9,10, because diamond has a much wider bandgap and is less sensitive to imperfections11,12. In addition, the bandgap in diamond crystals appears at a refractive index contrast of about 2, which means that a photonic bandgap could be achieved using known materials at optical frequencies; this does not seem to be possible for face-centred-cubic crystals3,13. However, self-assembly of colloidal diamond is challenging. Because particles in a diamond lattice are tetrahedrally coordinated, one approach has been to self-assemble spherical particles with tetrahedral sticky patches14–16. But this approach lacks a mechanism to ensure that the patchy spheres select the staggered orientation of tetrahedral bonds on nearest-neighbour particles, which is required for cubic diamond15,17. Here we show that by using partially compressed tetrahedral clusters with retracted sticky patches, colloidal cubic diamond can be self-assembled using patch–patch adhesion in combination with a steric interlock mechanism that selects the required staggered bond orientation. Photonic bandstructure calculations reveal that the resulting lattices (direct and inverse) have promising optical properties, including a wide and complete photonic bandgap. The colloidal particles in the self-assembled cubic diamond structure are highly constrained and mechanically stable, which makes it possible to dry the suspension and retain the diamond structure. This makes these structures suitable templates for forming high-dielectric-contrast photonic crystals with cubic diamond symmetry.

Original languageEnglish (US)
Pages (from-to)524-529
Number of pages6
JournalNature
Volume585
Issue number7826
DOIs
StatePublished - Sep 24 2020

ASJC Scopus subject areas

  • General

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    He, M., Gales, J. P., Ducrot, É., Gong, Z., Yi, G. R., Sacanna, S., & Pine, D. J. (2020). Colloidal diamond. Nature, 585(7826), 524-529. https://doi.org/10.1038/s41586-020-2718-6