Combined deuterium labeling and appearance potential measurements to uncover competing reaction mechanisms in the electron‐impact‐induced loss of water from cyclohexanol

Mark M. Green, Don Bafus, J. L. Franklin

Research output: Contribution to journalArticlepeer-review

Abstract

The appearance potentials for loss of H2O and DOH from the constitutional isomers 3,5‐dideuterocyclohexanol and 4,4‐ dideuterocyclohexannol show, in agreement with proposals based on stereoselectivites, that 1,3 loss of water is energetically more costly than 1,4 loss of water.

Original languageEnglish (US)
Pages (from-to)679-681
Number of pages3
JournalOrganic Mass Spectrometry
Volume10
Issue number8
DOIs
StatePublished - Aug 1975

ASJC Scopus subject areas

  • Biochemistry
  • Molecular Medicine
  • Instrumentation

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