Concentration dependence of solution viscosities of rigid rod polymers

T. K. Kwei, M. Nakazawa, S. Matsuoka, M. K. Cowman, Y. Okamoto

Research output: Contribution to journalArticle

Abstract

A series of poly(benzoyl-1,4-phenylene)s (PBP), with different molecular weights and microstructures that are soluble in organic solvents, was synthesized. By using different catalysts, PBP-II which contains both head-to-tail and head-to-head linkages, and PBP-I in which the repeating units are arranged predominantly in a head-to-tail fashion were synthesized. The intrinsic viscosity of PBP-I in dimethylacetamide is 0.57 dL/g, and the GPC (gel permeation chromatography) molecular weight is 2.65×104. The ratio of Mw/Mn from GPC data is 1.7 for PBP-II and 2.5 for PBP-I.

Original languageEnglish (US)
Pages (from-to)235-236
Number of pages2
JournalMacromolecules
Volume33
Issue number2
DOIs
StatePublished - 2000

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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