Conjugate addition of allyl stannanes with concomitant triflation

Ellen D. Beaulieu; Leah Voss; Dirk Trauner

doi:10.1021/ol702996t

Conjugate addition of allyl stannanes with concomitant triflation

Ellen D. Beaulieu, Leah Voss, Dirk Trauner

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A new method for the conjugate addition of allyltributylstannane with concomitant triflation is described. This reaction works with functionalized enones, enals, enoates, and vinylogous esters. The resulting vinyl triflates can be used for intramolecular Heck reactions to afford the products of 5-exo-trig cyclization.

Original language	English (US)
Pages (from-to)	869-872
Number of pages	4
Journal	Organic Letters
Volume	10
Issue number	5
DOIs	https://doi.org/10.1021/ol702996t
State	Published - Mar 6 2008

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.1021/ol702996t

Cite this

@article{b19e78a26d1e44afbf651f8b3a8ea641,

title = "Conjugate addition of allyl stannanes with concomitant triflation",

abstract = "A new method for the conjugate addition of allyltributylstannane with concomitant triflation is described. This reaction works with functionalized enones, enals, enoates, and vinylogous esters. The resulting vinyl triflates can be used for intramolecular Heck reactions to afford the products of 5-exo-trig cyclization.",

author = "Beaulieu, {Ellen D.} and Leah Voss and Dirk Trauner",

year = "2008",

month = mar,

day = "6",

doi = "10.1021/ol702996t",

language = "English (US)",

volume = "10",

pages = "869--872",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "5",

}

TY - JOUR

T1 - Conjugate addition of allyl stannanes with concomitant triflation

AU - Beaulieu, Ellen D.

AU - Voss, Leah

AU - Trauner, Dirk

PY - 2008/3/6

Y1 - 2008/3/6

N2 - A new method for the conjugate addition of allyltributylstannane with concomitant triflation is described. This reaction works with functionalized enones, enals, enoates, and vinylogous esters. The resulting vinyl triflates can be used for intramolecular Heck reactions to afford the products of 5-exo-trig cyclization.

AB - A new method for the conjugate addition of allyltributylstannane with concomitant triflation is described. This reaction works with functionalized enones, enals, enoates, and vinylogous esters. The resulting vinyl triflates can be used for intramolecular Heck reactions to afford the products of 5-exo-trig cyclization.

UR - http://www.scopus.com/inward/record.url?scp=43549087461&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=43549087461&partnerID=8YFLogxK

U2 - 10.1021/ol702996t

DO - 10.1021/ol702996t

M3 - Article

C2 - 18232702

AN - SCOPUS:43549087461

SN - 1523-7060

VL - 10

SP - 869

EP - 872

JO - Organic Letters

JF - Organic Letters

IS - 5

ER -

Conjugate addition of allyl stannanes with concomitant triflation

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this