Covalent and orthogonal multi-functionalization of terpolymers

Si Kyung Yang, Marcus Weck

Research output: Contribution to journalArticlepeer-review

Abstract

Random poly(norbornene)-based terpolymers containing azide, ketone and maleimide functionalities along the side-chain were synthesized using ring-opening metathesis polymerization. Subsequent side-chain functionalizations were carried out using three distinct reactions: maleimide-thiol coupling, 1,3-dipolar cycloaddition, and hydrazone formation. All investigated functionalization transformations proceed with high fidelity and absolute selectivity under mild reaction conditions.

Original languageEnglish (US)
Pages (from-to)582-585
Number of pages4
JournalSoft Matter
Volume5
Issue number3
DOIs
StatePublished - 2009

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics

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