Covalent and orthogonal multi-functionalization of terpolymers

Si Kyung Yang; Marcus Weck

doi:10.1039/b813675k

Covalent and orthogonal multi-functionalization of terpolymers

Si Kyung Yang, Marcus Weck

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Random poly(norbornene)-based terpolymers containing azide, ketone and maleimide functionalities along the side-chain were synthesized using ring-opening metathesis polymerization. Subsequent side-chain functionalizations were carried out using three distinct reactions: maleimide-thiol coupling, 1,3-dipolar cycloaddition, and hydrazone formation. All investigated functionalization transformations proceed with high fidelity and absolute selectivity under mild reaction conditions.

Original language	English (US)
Pages (from-to)	582-585
Number of pages	4
Journal	Soft Matter
Volume	5
Issue number	3
DOIs	https://doi.org/10.1039/b813675k
State	Published - 2009

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics

Access to Document

10.1039/b813675k

Cite this

@article{452608a3f25246ed82200c9178266652,

title = "Covalent and orthogonal multi-functionalization of terpolymers",

abstract = "Random poly(norbornene)-based terpolymers containing azide, ketone and maleimide functionalities along the side-chain were synthesized using ring-opening metathesis polymerization. Subsequent side-chain functionalizations were carried out using three distinct reactions: maleimide-thiol coupling, 1,3-dipolar cycloaddition, and hydrazone formation. All investigated functionalization transformations proceed with high fidelity and absolute selectivity under mild reaction conditions.",

author = "Yang, {Si Kyung} and Marcus Weck",

year = "2009",

doi = "10.1039/b813675k",

language = "English (US)",

volume = "5",

pages = "582--585",

journal = "Soft Matter",

issn = "1744-683X",

publisher = "Royal Society of Chemistry",

number = "3",

}

TY - JOUR

T1 - Covalent and orthogonal multi-functionalization of terpolymers

AU - Yang, Si Kyung

AU - Weck, Marcus

PY - 2009

Y1 - 2009

N2 - Random poly(norbornene)-based terpolymers containing azide, ketone and maleimide functionalities along the side-chain were synthesized using ring-opening metathesis polymerization. Subsequent side-chain functionalizations were carried out using three distinct reactions: maleimide-thiol coupling, 1,3-dipolar cycloaddition, and hydrazone formation. All investigated functionalization transformations proceed with high fidelity and absolute selectivity under mild reaction conditions.

AB - Random poly(norbornene)-based terpolymers containing azide, ketone and maleimide functionalities along the side-chain were synthesized using ring-opening metathesis polymerization. Subsequent side-chain functionalizations were carried out using three distinct reactions: maleimide-thiol coupling, 1,3-dipolar cycloaddition, and hydrazone formation. All investigated functionalization transformations proceed with high fidelity and absolute selectivity under mild reaction conditions.

UR - http://www.scopus.com/inward/record.url?scp=67649939001&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=67649939001&partnerID=8YFLogxK

U2 - 10.1039/b813675k

DO - 10.1039/b813675k

M3 - Article

AN - SCOPUS:67649939001

SN - 1744-683X

VL - 5

SP - 582

EP - 585

JO - Soft Matter

JF - Soft Matter

IS - 3

ER -

Covalent and orthogonal multi-functionalization of terpolymers

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this