TY - JOUR
T1 - Crystal structure and spectroscopic characterization of lithium saccharinate 11/6 hydrate, a hygroscopic and potentially physiologically active compound
AU - Naumov, Panče
AU - Jovanovski, Gligor
AU - Tančeva, Slavica
AU - Ng, Seik Weng
PY - 2006
Y1 - 2006
N2 - The structure of the only structurally yet uncharacterized alkali saccharinate, lithium saccharinate, is reported, together with the infrared spectra of its protonated and partially deuterated analogues. The compound crystallizes as strongly hygroscopic colorless triclinic crystal blocks of a 11/6 hydrate, LiC7H4NO3S·11/6H 2O, space group P1, with unit cell dimensions a = 10.070(1), b = 15.755(2), c = 19.134(2) Å, α = 68.085(2), β = 76.940(2), γ = 84.169(2)°, V = 2743.0(5) Å3 and Z = 12 at T = 200(2) K.
AB - The structure of the only structurally yet uncharacterized alkali saccharinate, lithium saccharinate, is reported, together with the infrared spectra of its protonated and partially deuterated analogues. The compound crystallizes as strongly hygroscopic colorless triclinic crystal blocks of a 11/6 hydrate, LiC7H4NO3S·11/6H 2O, space group P1, with unit cell dimensions a = 10.070(1), b = 15.755(2), c = 19.134(2) Å, α = 68.085(2), β = 76.940(2), γ = 84.169(2)°, V = 2743.0(5) Å3 and Z = 12 at T = 200(2) K.
KW - Lithium
KW - Saccharinate
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U2 - 10.1002/zaac.200500433
DO - 10.1002/zaac.200500433
M3 - Article
AN - SCOPUS:33144480258
SN - 0044-2313
VL - 632
SP - 454
EP - 460
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
IS - 3
ER -