Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate

Pance Naumov; Semiha Çakir; Iclal Bulut; Ender Bicer; Osman Çakir; Gligor Jovanovski; Abdul Razak Ibrahim; Anwar Usman; Hoong Kun Fun; Suchada Chantrapromma; Weng Ng Seik

doi:10.1515/MGMC.2002.25.3.175

Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate

Pance Naumov, Semiha Çakir, Iclal Bulut, Ender Bicer, Osman Çakir, Gligor Jovanovski, Abdul Razak Ibrahim, Anwar Usman, Hoong Kun Fun, Suchada Chantrapromma, Weng Ng Seik

Chemistry

Research output: Contribution to journal › Review article › peer-review

Abstract

In the lead disaccharinate-nicotinamide complex, the lead atom is covalently bonded to two carbonyl oxygen atoms. It is coordinated by the bridging nicotinamide molecule through the amido oxygen and pyridyl nitrogen atoms; however, the latter interaction is significantly weak [Pb-N 2.73(1) Å]. The bridging heterocyle links adjacent lead disaccharinate molecules into a chain running along the b-axis of the unit cell. A hydrogen bond connects the lattice water molecule to the negatively-charged imido nitrogen atom of the saccharinato entity of two adjacent lead disaccharinate molecules; the amido group also engages in hydrogen bonding interactions to furnish a layer structure.

Original language	English (US)
Pages (from-to)	175-176
Number of pages	2
Journal	Main Group Metal Chemistry
Volume	25
Issue number	3
DOIs	https://doi.org/10.1515/MGMC.2002.25.3.175
State	Published - 2002

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics
Metals and Alloys
Materials Chemistry

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10.1515/MGMC.2002.25.3.175

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@article{87d8141cb09e4015a839ce3215ceb305,

title = "Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate",

abstract = "In the lead disaccharinate-nicotinamide complex, the lead atom is covalently bonded to two carbonyl oxygen atoms. It is coordinated by the bridging nicotinamide molecule through the amido oxygen and pyridyl nitrogen atoms; however, the latter interaction is significantly weak [Pb-N 2.73(1) {\AA}]. The bridging heterocyle links adjacent lead disaccharinate molecules into a chain running along the b-axis of the unit cell. A hydrogen bond connects the lattice water molecule to the negatively-charged imido nitrogen atom of the saccharinato entity of two adjacent lead disaccharinate molecules; the amido group also engages in hydrogen bonding interactions to furnish a layer structure.",

author = "Pance Naumov and Semiha {\c C}akir and Iclal Bulut and Ender Bicer and Osman {\c C}akir and Gligor Jovanovski and Ibrahim, {Abdul Razak} and Anwar Usman and Fun, {Hoong Kun} and Suchada Chantrapromma and Seik, {Weng Ng}",

note = "Funding Information: We thank the National Science Council for R & D , Malaysia University of Malaya (F0758/2001 A) for supporting this work.",

year = "2002",

doi = "10.1515/MGMC.2002.25.3.175",

language = "English (US)",

volume = "25",

pages = "175--176",

journal = "Main Group Metal Chemistry",

issn = "0334-7575",

publisher = "Walter de Gruyter GmbH",

number = "3",

}

TY - JOUR

T1 - Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate

AU - Naumov, Pance

AU - Çakir, Semiha

AU - Bulut, Iclal

AU - Bicer, Ender

AU - Çakir, Osman

AU - Jovanovski, Gligor

AU - Ibrahim, Abdul Razak

AU - Usman, Anwar

AU - Fun, Hoong Kun

AU - Chantrapromma, Suchada

AU - Seik, Weng Ng

N1 - Funding Information: We thank the National Science Council for R & D , Malaysia University of Malaya (F0758/2001 A) for supporting this work.

PY - 2002

Y1 - 2002

N2 - In the lead disaccharinate-nicotinamide complex, the lead atom is covalently bonded to two carbonyl oxygen atoms. It is coordinated by the bridging nicotinamide molecule through the amido oxygen and pyridyl nitrogen atoms; however, the latter interaction is significantly weak [Pb-N 2.73(1) Å]. The bridging heterocyle links adjacent lead disaccharinate molecules into a chain running along the b-axis of the unit cell. A hydrogen bond connects the lattice water molecule to the negatively-charged imido nitrogen atom of the saccharinato entity of two adjacent lead disaccharinate molecules; the amido group also engages in hydrogen bonding interactions to furnish a layer structure.

AB - In the lead disaccharinate-nicotinamide complex, the lead atom is covalently bonded to two carbonyl oxygen atoms. It is coordinated by the bridging nicotinamide molecule through the amido oxygen and pyridyl nitrogen atoms; however, the latter interaction is significantly weak [Pb-N 2.73(1) Å]. The bridging heterocyle links adjacent lead disaccharinate molecules into a chain running along the b-axis of the unit cell. A hydrogen bond connects the lattice water molecule to the negatively-charged imido nitrogen atom of the saccharinato entity of two adjacent lead disaccharinate molecules; the amido group also engages in hydrogen bonding interactions to furnish a layer structure.

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U2 - 10.1515/MGMC.2002.25.3.175

DO - 10.1515/MGMC.2002.25.3.175

M3 - Review article

AN - SCOPUS:0036395649

SN - 0334-7575

VL - 25

SP - 175

EP - 176

JO - Main Group Metal Chemistry

JF - Main Group Metal Chemistry

IS - 3

ER -

Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate

Abstract

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