Dearomatization reactions of aryl-substituted silaaziridines

Zulimar Nevárez, K. A. Woerpel

Research output: Contribution to journalArticlepeer-review

Abstract

(Chemical Equation Presented) Silaaziridines with an aryl group on either the carbon or the nitrogen atom undergo dearomatization reactions upon treatment with benzaldehyde. The reactions form new bonds ortho to the nitrogen substituents with high diastereoselectivity. These dearomatization processes likely are driven by relief of the considerable ring strain of the silaaziridine.

Original languageEnglish (US)
Pages (from-to)8113-8115
Number of pages3
JournalJournal of Organic Chemistry
Volume73
Issue number20
DOIs
StatePublished - Oct 17 2008

ASJC Scopus subject areas

  • Organic Chemistry

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