Dearomatization reactions of aryl-substituted silaaziridines

Zulimar Nevárez; K. A. Woerpel

doi:10.1021/jo801502x

Dearomatization reactions of aryl-substituted silaaziridines

Zulimar Nevárez, K. A. Woerpel

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

(Chemical Equation Presented) Silaaziridines with an aryl group on either the carbon or the nitrogen atom undergo dearomatization reactions upon treatment with benzaldehyde. The reactions form new bonds ortho to the nitrogen substituents with high diastereoselectivity. These dearomatization processes likely are driven by relief of the considerable ring strain of the silaaziridine.

Original language	English (US)
Pages (from-to)	8113-8115
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	73
Issue number	20
DOIs	https://doi.org/10.1021/jo801502x
State	Published - Oct 17 2008

ASJC Scopus subject areas

Organic Chemistry

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title = "Dearomatization reactions of aryl-substituted silaaziridines",

abstract = "(Chemical Equation Presented) Silaaziridines with an aryl group on either the carbon or the nitrogen atom undergo dearomatization reactions upon treatment with benzaldehyde. The reactions form new bonds ortho to the nitrogen substituents with high diastereoselectivity. These dearomatization processes likely are driven by relief of the considerable ring strain of the silaaziridine.",

author = "Zulimar Nev{\'a}rez and Woerpel, {K. A.}",

year = "2008",

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doi = "10.1021/jo801502x",

language = "English (US)",

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AU - Woerpel, K. A.

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N2 - (Chemical Equation Presented) Silaaziridines with an aryl group on either the carbon or the nitrogen atom undergo dearomatization reactions upon treatment with benzaldehyde. The reactions form new bonds ortho to the nitrogen substituents with high diastereoselectivity. These dearomatization processes likely are driven by relief of the considerable ring strain of the silaaziridine.

AB - (Chemical Equation Presented) Silaaziridines with an aryl group on either the carbon or the nitrogen atom undergo dearomatization reactions upon treatment with benzaldehyde. The reactions form new bonds ortho to the nitrogen substituents with high diastereoselectivity. These dearomatization processes likely are driven by relief of the considerable ring strain of the silaaziridine.

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Dearomatization reactions of aryl-substituted silaaziridines

Abstract

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