Abstract
An overcomplete density functional formalism is derived to represent the thermal behaviour of confined classical fluids under single-file conditions. Strictly one-dimensional hard rod systems are reanalysed from this viewpoint, and the context is then broadened to encompass hard spheres in cylindrical enclosures. Applications to non-single-file conditions, modulated enclosures, and confined polymers are mentioned.
Original language | English (US) |
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Pages (from-to) | 2417-2422 |
Number of pages | 6 |
Journal | Molecular Physics |
Volume | 100 |
Issue number | 15 |
DOIs | |
State | Published - Aug 10 2002 |
ASJC Scopus subject areas
- Biophysics
- Molecular Biology
- Condensed Matter Physics
- Physical and Theoretical Chemistry