Designing a helical polymer that reverses handedness at a selected, continuously variable, temperature

Kap Soo Cheon; Jonathan V. Selinger; Mark M. Green

Designing a helical polymer that reverses handedness at a selected, continuously variable, temperature

Kap Soo Cheon, Jonathan V. Selinger, Mark M. Green

Chemical and Biomolecular Engineering

Research output: Contribution to journal › Conference article › peer-review

Abstract

A theory is developed to explain how the optical activity of polymers composed of mirror-image units depended on enantiomeric excess around the 50/50 racemic point. The theory is generalized to describe the polymers consisting of competing chiral units. The polymer is described by the random-field Ising model, with the quenched random field representing the local chiral bias of each monomer.

Original language	English (US)
Pages (from-to)	957-958
Number of pages	2
Journal	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume	41
Issue number	1
State	Published - Mar 2000
Event	The San Francisco Meeting - San Francisco, CA, USA Duration: Mar 26 2000 → Mar 31 2000

ASJC Scopus subject areas

Polymers and Plastics

Cite this

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title = "Designing a helical polymer that reverses handedness at a selected, continuously variable, temperature",

abstract = "A theory is developed to explain how the optical activity of polymers composed of mirror-image units depended on enantiomeric excess around the 50/50 racemic point. The theory is generalized to describe the polymers consisting of competing chiral units. The polymer is described by the random-field Ising model, with the quenched random field representing the local chiral bias of each monomer.",

author = "Cheon, {Kap Soo} and Selinger, {Jonathan V.} and Green, {Mark M.}",

year = "2000",

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AU - Cheon, Kap Soo

AU - Selinger, Jonathan V.

AU - Green, Mark M.

PY - 2000/3

Y1 - 2000/3

N2 - A theory is developed to explain how the optical activity of polymers composed of mirror-image units depended on enantiomeric excess around the 50/50 racemic point. The theory is generalized to describe the polymers consisting of competing chiral units. The polymer is described by the random-field Ising model, with the quenched random field representing the local chiral bias of each monomer.

AB - A theory is developed to explain how the optical activity of polymers composed of mirror-image units depended on enantiomeric excess around the 50/50 racemic point. The theory is generalized to describe the polymers consisting of competing chiral units. The polymer is described by the random-field Ising model, with the quenched random field representing the local chiral bias of each monomer.

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M3 - Conference article

AN - SCOPUS:0033734085

SN - 0032-3934

VL - 41

SP - 957

EP - 958

JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

IS - 1

T2 - The San Francisco Meeting

Y2 - 26 March 2000 through 31 March 2000

ER -

Designing a helical polymer that reverses handedness at a selected, continuously variable, temperature

Abstract

ASJC Scopus subject areas

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