Diastereoselective peroxidation of derivatives of Baylis–Hillman adducts

Dylan S. Zuckerman, K. A. Woerpel

Research output: Contribution to journalArticle

Abstract

Cyclic derivatives of Baylis–Hillman adducts were synthesized. Cobalt-catalyzed peroxidation of these cyclic lactones afforded silyl peroxides in diastereomeric ratios ranging from 91:9 to 97:3.

Original languageEnglish (US)
Pages (from-to)4118-4129
Number of pages12
JournalTetrahedron
Volume75
Issue number31
DOIs
StatePublished - Aug 2 2019

Keywords

  • Catalysis
  • Cobalt
  • Diastereoselective
  • Peroxide
  • Radical

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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