@article{32c51b3102064b818513add0d5e1df8b,
title = "Diastereoselective peroxidation of derivatives of Baylis–Hillman adducts",
abstract = "Cyclic derivatives of Baylis–Hillman adducts were synthesized. Cobalt-catalyzed peroxidation of these cyclic lactones afforded silyl peroxides in diastereomeric ratios ranging from 91:9 to 97:3.",
keywords = "Catalysis, Cobalt, Diastereoselective, Peroxide, Radical",
author = "Zuckerman, {Dylan S.} and Woerpel, {K. A.}",
note = "Funding Information: This research was supported by the National Institute of General Medical Sciences of the National Institutes of Health ( 1R01GM118730 ). D.S.Z. thanks the NYU Department of Chemistry for support in the form of a Margaret Strauss Kramer Fellowship. NMR spectra acquired with the TCI cryoprobe and Bruker Avance 400 spectrometer were supported by the National Institutes of Health ( OD016343 ) and the National Science Foundation ( CHE-01162222 ), respectively. The authors thank Dr. Chin Lin for his assistance with NMR spectroscopy and mass spectrometry, Jonathan Oswald for synthesizing the cobalt catalysts, David Anthony for obtaining preliminary data, and Ana Burris for technical assistance. Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",
year = "2019",
month = aug,
day = "2",
doi = "10.1016/j.tet.2019.05.008",
language = "English (US)",
volume = "75",
pages = "4118--4129",
journal = "Tetrahedron",
issn = "0040-4020",
publisher = "Elsevier Limited",
number = "31",
}