Abstract
Cyclic derivatives of Baylis–Hillman adducts were synthesized. Cobalt-catalyzed peroxidation of these cyclic lactones afforded silyl peroxides in diastereomeric ratios ranging from 91:9 to 97:3.
Original language | English (US) |
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Pages (from-to) | 4118-4129 |
Number of pages | 12 |
Journal | Tetrahedron |
Volume | 75 |
Issue number | 31 |
DOIs | |
State | Published - Aug 2 2019 |
Keywords
- Catalysis
- Cobalt
- Diastereoselective
- Peroxide
- Radical
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry