Abstract
Most NMR-active nuclei found in the periodic table have a quadrupole moment. In combination with a nonsymmetric electron distribution a strong NMR-active interaction results, which very often overshadows the dipolar and scalar couplings. This article aims at reviewing how these interactions manifest themselves in quadrupolar NMR and how they can be exploited for resonance assignment and structure elucidation, in spite of the presence of a strong quadrupolar interaction.
Original language | English (US) |
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Pages (from-to) | 1481-1496 |
Number of pages | 16 |
Journal | Monatshefte fur Chemie |
Volume | 133 |
Issue number | 12 |
DOIs | |
State | Published - 2002 |
Keywords
- Dipolar couplings
- NMR spectroscopy
- Quadrupolar couplings
- Solid-state
ASJC Scopus subject areas
- General Chemistry