Direct imaging by atomic force microscopy of surface-localized self-assembled monolayers on a cuprate superconductor and surface X-ray scattering analysis of analogous monolayers on the surface of water

Steen B. Schougaard; Niels Reitzel; Thomas Bjørnholm; Kristian Kjaer; Torben R. Jensen; Olga E. Shmakova; Ramon Colorado; T. Randall Lee; J. H. Choi; John T. Markert; David Derro; Alex de Lozanne; John T. McDevitt

doi:10.1016/j.tsf.2007.04.034

Direct imaging by atomic force microscopy of surface-localized self-assembled monolayers on a cuprate superconductor and surface X-ray scattering analysis of analogous monolayers on the surface of water

Steen B. Schougaard, Niels Reitzel, Thomas Bjørnholm, Kristian Kjaer, Torben R. Jensen, Olga E. Shmakova, Ramon Colorado, T. Randall Lee, J. H. Choi, John T. Markert, David Derro, Alex de Lozanne, John T. McDevitt

Research output: Contribution to journal › Article › peer-review

Abstract

A self-assembled monolayer of CF₃(CF₂)₃(CH₂)₁₁N H₂ atop the (001) surface of the high-temperature superconductor YBa₂Cu₃O_7-x was imaged by atomic force microscopy (AFM). The AFM images provide direct 2D-structural evidence for the epitaxial 5.5 Å square √2 × √2R45° unit cell previously predicted for alkyl amines by molecular modeling [J.E. Ritchie, C.A. Wells, J.-P. Zhou, J. Zhao, J.T. McDevitt, C.R. Ankrum, L. Jean, D.R. Kanis, J. Am. Chem. Soc. 120 (1998) 2733]. Additionally, the 3D structure of an analogous Langmuir monolayer of CF₃(CF₂)₉(CH₂)₁₁N H₂ on water was studied by grazing-incidence X-ray diffraction and specular X-ray reflectivity. Structural differences and similarities between the water-supported and superconductor-localized monolayers are discussed.

Original language	English (US)
Pages (from-to)	8424-8429
Number of pages	6
Journal	Thin Solid Films
Volume	515
Issue number	23
DOIs	https://doi.org/10.1016/j.tsf.2007.04.034
State	Published - Sep 14 2007

Keywords

Atomic force microscopy
Grazing-incidence X-ray diffraction (GIXD)
Self-assembled monolayers (SAMs)
Surface composition

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Surfaces and Interfaces
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1016/j.tsf.2007.04.034

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Schougaard, S. B., Reitzel, N., Bjørnholm, T., Kjaer, K., Jensen, T. R., Shmakova, O. E., Colorado, R., Lee, T. R., Choi, J. H., Markert, J. T., Derro, D., de Lozanne, A., & McDevitt, J. T. (2007). Direct imaging by atomic force microscopy of surface-localized self-assembled monolayers on a cuprate superconductor and surface X-ray scattering analysis of analogous monolayers on the surface of water. Thin Solid Films, 515(23), 8424-8429. https://doi.org/10.1016/j.tsf.2007.04.034

Direct imaging by atomic force microscopy of surface-localized self-assembled monolayers on a cuprate superconductor and surface X-ray scattering analysis of analogous monolayers on the surface of water. / Schougaard, Steen B.; Reitzel, Niels; Bjørnholm, Thomas et al.
In: Thin Solid Films, Vol. 515, No. 23, 14.09.2007, p. 8424-8429.

Research output: Contribution to journal › Article › peer-review

Schougaard, SB, Reitzel, N, Bjørnholm, T, Kjaer, K, Jensen, TR, Shmakova, OE, Colorado, R, Lee, TR, Choi, JH, Markert, JT, Derro, D, de Lozanne, A & McDevitt, JT 2007, 'Direct imaging by atomic force microscopy of surface-localized self-assembled monolayers on a cuprate superconductor and surface X-ray scattering analysis of analogous monolayers on the surface of water', Thin Solid Films, vol. 515, no. 23, pp. 8424-8429. https://doi.org/10.1016/j.tsf.2007.04.034

@article{7bd45e0a829d489b95ce99172818c976,

title = "Direct imaging by atomic force microscopy of surface-localized self-assembled monolayers on a cuprate superconductor and surface X-ray scattering analysis of analogous monolayers on the surface of water",

abstract = "A self-assembled monolayer of CF3(CF2)3(CH2)11N H2 atop the (001) surface of the high-temperature superconductor YBa2Cu3O7-x was imaged by atomic force microscopy (AFM). The AFM images provide direct 2D-structural evidence for the epitaxial 5.5 {\AA} square √2 × √2R45° unit cell previously predicted for alkyl amines by molecular modeling [J.E. Ritchie, C.A. Wells, J.-P. Zhou, J. Zhao, J.T. McDevitt, C.R. Ankrum, L. Jean, D.R. Kanis, J. Am. Chem. Soc. 120 (1998) 2733]. Additionally, the 3D structure of an analogous Langmuir monolayer of CF3(CF2)9(CH2)11N H2 on water was studied by grazing-incidence X-ray diffraction and specular X-ray reflectivity. Structural differences and similarities between the water-supported and superconductor-localized monolayers are discussed.",

keywords = "Atomic force microscopy, Grazing-incidence X-ray diffraction (GIXD), Self-assembled monolayers (SAMs), Surface composition",

author = "Schougaard, {Steen B.} and Niels Reitzel and Thomas Bj{\o}rnholm and Kristian Kjaer and Jensen, {Torben R.} and Shmakova, {Olga E.} and Ramon Colorado and Lee, {T. Randall} and Choi, {J. H.} and Markert, {John T.} and David Derro and {de Lozanne}, Alex and McDevitt, {John T.}",

note = "Funding Information: J. T. McDevitt thanks the AFOSR, NSF (DMR-0211150), TCSUH, and the Welch Foundation for support. S. B. Schougaard thanks the Danish Research Agency for financial support. K. Kjaer thanks the Carlsberg Foundation for financial support. A. de Lozanne thanks the NSF (DMR-0308575) and the Welch Foundation (F-1533) for support. The synchrotron X-ray studies benefited from access to beamline BW1 at HASYLAB at DESY, Hamburg, Germany under the IHP-Contract HPRI-CT-1999-00040/2001-00140 of the European Commission and from support by the Danish Natural Science Research Council's DANSYNC program. T. R. Lee thanks the NSF (DMR-0447588), the Texas Center for Superconductivity, and the Welch Foundation (E-1320) for support. J. T. Markert also thanks the Welch Foundation (F-1191) for support. Dr. D. W. Breiby, Dr. D. A. Vanden Bout, Dr. C. Wells and Dr. J. Mauzeroll are gratefully acknowledged for discussions. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.",

year = "2007",

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doi = "10.1016/j.tsf.2007.04.034",

language = "English (US)",

volume = "515",

pages = "8424--8429",

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T1 - Direct imaging by atomic force microscopy of surface-localized self-assembled monolayers on a cuprate superconductor and surface X-ray scattering analysis of analogous monolayers on the surface of water

AU - Schougaard, Steen B.

AU - Reitzel, Niels

AU - Bjørnholm, Thomas

AU - Kjaer, Kristian

AU - Jensen, Torben R.

AU - Shmakova, Olga E.

AU - Colorado, Ramon

AU - Lee, T. Randall

AU - Choi, J. H.

AU - Markert, John T.

AU - Derro, David

AU - de Lozanne, Alex

AU - McDevitt, John T.

N1 - Funding Information: J. T. McDevitt thanks the AFOSR, NSF (DMR-0211150), TCSUH, and the Welch Foundation for support. S. B. Schougaard thanks the Danish Research Agency for financial support. K. Kjaer thanks the Carlsberg Foundation for financial support. A. de Lozanne thanks the NSF (DMR-0308575) and the Welch Foundation (F-1533) for support. The synchrotron X-ray studies benefited from access to beamline BW1 at HASYLAB at DESY, Hamburg, Germany under the IHP-Contract HPRI-CT-1999-00040/2001-00140 of the European Commission and from support by the Danish Natural Science Research Council's DANSYNC program. T. R. Lee thanks the NSF (DMR-0447588), the Texas Center for Superconductivity, and the Welch Foundation (E-1320) for support. J. T. Markert also thanks the Welch Foundation (F-1191) for support. Dr. D. W. Breiby, Dr. D. A. Vanden Bout, Dr. C. Wells and Dr. J. Mauzeroll are gratefully acknowledged for discussions. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.

PY - 2007/9/14

Y1 - 2007/9/14

N2 - A self-assembled monolayer of CF3(CF2)3(CH2)11N H2 atop the (001) surface of the high-temperature superconductor YBa2Cu3O7-x was imaged by atomic force microscopy (AFM). The AFM images provide direct 2D-structural evidence for the epitaxial 5.5 Å square √2 × √2R45° unit cell previously predicted for alkyl amines by molecular modeling [J.E. Ritchie, C.A. Wells, J.-P. Zhou, J. Zhao, J.T. McDevitt, C.R. Ankrum, L. Jean, D.R. Kanis, J. Am. Chem. Soc. 120 (1998) 2733]. Additionally, the 3D structure of an analogous Langmuir monolayer of CF3(CF2)9(CH2)11N H2 on water was studied by grazing-incidence X-ray diffraction and specular X-ray reflectivity. Structural differences and similarities between the water-supported and superconductor-localized monolayers are discussed.

AB - A self-assembled monolayer of CF3(CF2)3(CH2)11N H2 atop the (001) surface of the high-temperature superconductor YBa2Cu3O7-x was imaged by atomic force microscopy (AFM). The AFM images provide direct 2D-structural evidence for the epitaxial 5.5 Å square √2 × √2R45° unit cell previously predicted for alkyl amines by molecular modeling [J.E. Ritchie, C.A. Wells, J.-P. Zhou, J. Zhao, J.T. McDevitt, C.R. Ankrum, L. Jean, D.R. Kanis, J. Am. Chem. Soc. 120 (1998) 2733]. Additionally, the 3D structure of an analogous Langmuir monolayer of CF3(CF2)9(CH2)11N H2 on water was studied by grazing-incidence X-ray diffraction and specular X-ray reflectivity. Structural differences and similarities between the water-supported and superconductor-localized monolayers are discussed.

KW - Atomic force microscopy

KW - Grazing-incidence X-ray diffraction (GIXD)

KW - Self-assembled monolayers (SAMs)

KW - Surface composition

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Direct imaging by atomic force microscopy of surface-localized self-assembled monolayers on a cuprate superconductor and surface X-ray scattering analysis of analogous monolayers on the surface of water

Abstract

Keywords

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