Dyeing KDP

J. Anand Subramony; Sei Hum Jang; Bart Kahr

doi:10.1080/00150199708015653

Dyeing KDP

J. Anand Subramony, Sei Hum Jang, Bart Kahr

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We describe the growth and spectroscopy of well-defined mixed crystals of KH₂PO₄ (KDP) containing both natural and synthetic organic dyes in the {010} and {101} growth sectors. Our summary reevaluates historical dye inclusions, reveals others discovered in a directed screening, and ultimately describes dyes rationally synthesized for the recognition of KDP surfaces. Absorption and emission spectroscopies with polarized light are used to characterize these mixed crystals. A model that accounts for the facial selectivity of the dyes is proposed. We show that a chiral chromophore is selective enough to distinguish enantiomorphous faces of KDP. Tailor-made dye inclusions in KDP suggest the possibility of developing new photonic materials by coupling the optical properties of the host and guest.

Original language	English (US)
Pages (from-to)	293-300
Number of pages	8
Journal	Ferroelectrics
Volume	191
Issue number	1-4
DOIs	https://doi.org/10.1080/00150199708015653
State	Published - 1997

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics

Access to Document

10.1080/00150199708015653

Cite this

@article{8f44e9b6627347f6ba0d792fa308c751,

title = "Dyeing KDP",

abstract = "We describe the growth and spectroscopy of well-defined mixed crystals of KH2PO4 (KDP) containing both natural and synthetic organic dyes in the {010} and {101} growth sectors. Our summary reevaluates historical dye inclusions, reveals others discovered in a directed screening, and ultimately describes dyes rationally synthesized for the recognition of KDP surfaces. Absorption and emission spectroscopies with polarized light are used to characterize these mixed crystals. A model that accounts for the facial selectivity of the dyes is proposed. We show that a chiral chromophore is selective enough to distinguish enantiomorphous faces of KDP. Tailor-made dye inclusions in KDP suggest the possibility of developing new photonic materials by coupling the optical properties of the host and guest.",

author = "{Anand Subramony}, J. and Jang, {Sei Hum} and Bart Kahr",

year = "1997",

doi = "10.1080/00150199708015653",

language = "English (US)",

volume = "191",

pages = "293--300",

journal = "Ferroelectrics",

issn = "0015-0193",

publisher = "Taylor and Francis Ltd.",

number = "1-4",

}

TY - JOUR

T1 - Dyeing KDP

AU - Anand Subramony, J.

AU - Jang, Sei Hum

AU - Kahr, Bart

PY - 1997

Y1 - 1997

N2 - We describe the growth and spectroscopy of well-defined mixed crystals of KH2PO4 (KDP) containing both natural and synthetic organic dyes in the {010} and {101} growth sectors. Our summary reevaluates historical dye inclusions, reveals others discovered in a directed screening, and ultimately describes dyes rationally synthesized for the recognition of KDP surfaces. Absorption and emission spectroscopies with polarized light are used to characterize these mixed crystals. A model that accounts for the facial selectivity of the dyes is proposed. We show that a chiral chromophore is selective enough to distinguish enantiomorphous faces of KDP. Tailor-made dye inclusions in KDP suggest the possibility of developing new photonic materials by coupling the optical properties of the host and guest.

AB - We describe the growth and spectroscopy of well-defined mixed crystals of KH2PO4 (KDP) containing both natural and synthetic organic dyes in the {010} and {101} growth sectors. Our summary reevaluates historical dye inclusions, reveals others discovered in a directed screening, and ultimately describes dyes rationally synthesized for the recognition of KDP surfaces. Absorption and emission spectroscopies with polarized light are used to characterize these mixed crystals. A model that accounts for the facial selectivity of the dyes is proposed. We show that a chiral chromophore is selective enough to distinguish enantiomorphous faces of KDP. Tailor-made dye inclusions in KDP suggest the possibility of developing new photonic materials by coupling the optical properties of the host and guest.

UR - http://www.scopus.com/inward/record.url?scp=0030695667&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0030695667&partnerID=8YFLogxK

U2 - 10.1080/00150199708015653

DO - 10.1080/00150199708015653

M3 - Article

AN - SCOPUS:0030695667

SN - 0015-0193

VL - 191

SP - 293

EP - 300

JO - Ferroelectrics

JF - Ferroelectrics

IS - 1-4

ER -

Dyeing KDP

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this