Dynamic stereoisomerization in inherently chiral bimetallic [2]catenanes

Thirumurugan Prakasam; Matteo Lusi; Elisa Nauha; John Carl Olsen; Mohamadou Sy; Carlos Platas-Iglesias; Loïc J. Charbonnière; Ali Trabolsi

doi:10.1039/c4cc07392d

Dynamic stereoisomerization in inherently chiral bimetallic [2]catenanes

Thirumurugan Prakasam, Matteo Lusi, Elisa Nauha, John Carl Olsen, Mohamadou Sy, Carlos Platas-Iglesias, Loïc J. Charbonnière, Ali Trabolsi

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Stereoisomerization and the unprecedented phenomenon of metal translocation in the absence of redox processes were probed in two inherently chiral bimetallic [2]catenanes by using a combination of variableerature ¹H NMR and CD spectroscopies, X-ray crystallography, and DFT calculations.

Original language	English (US)
Pages (from-to)	5840-5843
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	27
DOIs	https://doi.org/10.1039/c4cc07392d
State	Published - Apr 7 2015

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c4cc07392d

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abstract = "Stereoisomerization and the unprecedented phenomenon of metal translocation in the absence of redox processes were probed in two inherently chiral bimetallic [2]catenanes by using a combination of variableerature 1H NMR and CD spectroscopies, X-ray crystallography, and DFT calculations.",

author = "Thirumurugan Prakasam and Matteo Lusi and Elisa Nauha and Olsen, {John Carl} and Mohamadou Sy and Carlos Platas-Iglesias and Charbonni{\`e}re, {Lo{\"i}c J.} and Ali Trabolsi",

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AU - Prakasam, Thirumurugan

AU - Lusi, Matteo

AU - Nauha, Elisa

AU - Olsen, John Carl

AU - Sy, Mohamadou

AU - Platas-Iglesias, Carlos

AU - Charbonnière, Loïc J.

AU - Trabolsi, Ali

PY - 2015/4/7

Y1 - 2015/4/7

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AB - Stereoisomerization and the unprecedented phenomenon of metal translocation in the absence of redox processes were probed in two inherently chiral bimetallic [2]catenanes by using a combination of variableerature 1H NMR and CD spectroscopies, X-ray crystallography, and DFT calculations.

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JO - Chemical Communications

JF - Chemical Communications

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Dynamic stereoisomerization in inherently chiral bimetallic [2]catenanes

Abstract

ASJC Scopus subject areas

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