Dynamic stereoisomerization in inherently chiral bimetallic [2]catenanes

Thirumurugan Prakasam, Matteo Lusi, Elisa Nauha, John Carl Olsen, Mohamadou Sy, Carlos Platas-Iglesias, Loïc J. Charbonnière, Ali Trabolsi

Research output: Contribution to journalArticle

Abstract

Stereoisomerization and the unprecedented phenomenon of metal translocation in the absence of redox processes were probed in two inherently chiral bimetallic [2]catenanes by using a combination of variableerature 1H NMR and CD spectroscopies, X-ray crystallography, and DFT calculations.

Original languageEnglish (US)
Pages (from-to)5840-5843
Number of pages4
JournalChemical Communications
Volume51
Issue number27
DOIs
StatePublished - Apr 7 2015

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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  • Cite this

    Prakasam, T., Lusi, M., Nauha, E., Olsen, J. C., Sy, M., Platas-Iglesias, C., Charbonnière, L. J., & Trabolsi, A. (2015). Dynamic stereoisomerization in inherently chiral bimetallic [2]catenanes. Chemical Communications, 51(27), 5840-5843. https://doi.org/10.1039/c4cc07392d