Dynamics of I=3/2 nuclei in isotropic slow motion, anisotropic and partially ordered phases

S. Chandra Shekar; Joel A. Tang; Alexej Jerschow

doi:10.1002/cmr.a.20195

Dynamics of I=3/2 nuclei in isotropic slow motion, anisotropic and partially ordered phases

S. Chandra Shekar, Joel A. Tang, Alexej Jerschow

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

NMR of quadrupolar nuclei, and, in particular ²³Na in soft tissues has attracted renewed interest due to the importance that sodium plays in physiology. The quadrupolar coupling and relaxation dynamics, including the appearance of the dynamic frequency shift are treated in this article. The equations governing irreducible spherical tensor analysis are derived and discussed. Experiments are shown to demonstrate how parameters such as the correlation time, the instantaneous and the residual quadrupolar couplings can be extracted from the data. Such experiments and procedures are particularly useful in the analysis of ²³Na NMR data from tissues or cell suspensions.

Original language	English (US)
Pages (from-to)	362-387
Number of pages	26
Journal	Concepts in Magnetic Resonance Part A: Bridging Education and Research
Volume	36 A
Issue number	6
DOIs	https://doi.org/10.1002/cmr.a.20195
State	Published - Nov 2010

Keywords

Anisotropic relaxation dynamics
Bacteriophage and cartilage
I = 3/2 and quadrupolar
Irreducible tensor analysis (STA) and multiple quantum filter
Order and disorder
Slow motion

ASJC Scopus subject areas

Spectroscopy

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title = "Dynamics of I=3/2 nuclei in isotropic slow motion, anisotropic and partially ordered phases",

abstract = "NMR of quadrupolar nuclei, and, in particular 23Na in soft tissues has attracted renewed interest due to the importance that sodium plays in physiology. The quadrupolar coupling and relaxation dynamics, including the appearance of the dynamic frequency shift are treated in this article. The equations governing irreducible spherical tensor analysis are derived and discussed. Experiments are shown to demonstrate how parameters such as the correlation time, the instantaneous and the residual quadrupolar couplings can be extracted from the data. Such experiments and procedures are particularly useful in the analysis of 23Na NMR data from tissues or cell suspensions.",

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AU - Shekar, S. Chandra

AU - Tang, Joel A.

AU - Jerschow, Alexej

PY - 2010/11

Y1 - 2010/11

N2 - NMR of quadrupolar nuclei, and, in particular 23Na in soft tissues has attracted renewed interest due to the importance that sodium plays in physiology. The quadrupolar coupling and relaxation dynamics, including the appearance of the dynamic frequency shift are treated in this article. The equations governing irreducible spherical tensor analysis are derived and discussed. Experiments are shown to demonstrate how parameters such as the correlation time, the instantaneous and the residual quadrupolar couplings can be extracted from the data. Such experiments and procedures are particularly useful in the analysis of 23Na NMR data from tissues or cell suspensions.

AB - NMR of quadrupolar nuclei, and, in particular 23Na in soft tissues has attracted renewed interest due to the importance that sodium plays in physiology. The quadrupolar coupling and relaxation dynamics, including the appearance of the dynamic frequency shift are treated in this article. The equations governing irreducible spherical tensor analysis are derived and discussed. Experiments are shown to demonstrate how parameters such as the correlation time, the instantaneous and the residual quadrupolar couplings can be extracted from the data. Such experiments and procedures are particularly useful in the analysis of 23Na NMR data from tissues or cell suspensions.

KW - Anisotropic relaxation dynamics

KW - Bacteriophage and cartilage

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KW - Irreducible tensor analysis (STA) and multiple quantum filter

KW - Order and disorder

KW - Slow motion

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Dynamics of I=3/2 nuclei in isotropic slow motion, anisotropic and partially ordered phases

Abstract

Keywords

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