Electron impact ionization cross-sections of SF3 and SF 5

W. M. Huo, V. Tarnovsky, K. Becker

Research output: Contribution to journalArticle

Abstract

We report experimental and theoretical studies of the total electron impact ionization cross-sections for the radicals SF3 and SF5. It is shown that for radicals with strongly polar fluoride bonds, the shielding of the attractive dipole interaction potential in the bonding region is important in a proper description of the collision process. The siBED model, which has incorporated the shielding factor, was found to provide cross-sections in agreement with recently re-analyzed experimental data for the species CFx and NFx (x=1-3), whereas the DM model and the BEB model, on the other hand, showed large discrepancies with experiment. These findings also hold for the two free radicals SF3 and SF5 studied here, providing further evidence on the importance of a proper shielding of the dipole potential.

Original languageEnglish (US)
Pages (from-to)111-116
Number of pages6
JournalInternational Journal of Mass Spectrometry
Volume233
Issue number1-3
DOIs
StatePublished - Apr 15 2004

Keywords

  • Cross-sections
  • Electron ionization
  • Free radicals
  • Plasma processing

ASJC Scopus subject areas

  • Instrumentation
  • Condensed Matter Physics
  • Spectroscopy
  • Physical and Theoretical Chemistry

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