Experimental measurements of low-Frequency intermolecular host-guest dynamics

Alexander P. Sukharevsky; Ian Read; Brian Linton; Andrew D. Hamilton; David H. Waldeck

Experimental measurements of low-Frequency intermolecular host-guest dynamics

Alexander P. Sukharevsky, Ian Read, Brian Linton, Andrew D. Hamilton, David H. Waldeck

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A direct temporal measurement of the internal motion of a host-guest bimolecular complex is reported. Time-resolved polarization spectroscopy is used to monitor the motion of a guest chromophore, anthracene-1,3-dicarboxylate, bound to a bis(guanidinium) host molecule through a combination of hydrogen bonding and electrostatic forces. The dynamics of the bound chromophore is well described by an overdamped oscillator model. Through simple modeling, it is possible to estimate the frequency of the host-guest potential and the range of the guest chromophore's angular displacement.

Original language	English (US)
Pages (from-to)	5394-5403
Number of pages	10
Journal	Journal of Physical Chemistry B
Volume	102
Issue number	27
State	Published - Jul 2 1998

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

Cite this

@article{17e3c082c83b42169fbd83ed359a9693,

title = "Experimental measurements of low-Frequency intermolecular host-guest dynamics",

abstract = "A direct temporal measurement of the internal motion of a host-guest bimolecular complex is reported. Time-resolved polarization spectroscopy is used to monitor the motion of a guest chromophore, anthracene-1,3-dicarboxylate, bound to a bis(guanidinium) host molecule through a combination of hydrogen bonding and electrostatic forces. The dynamics of the bound chromophore is well described by an overdamped oscillator model. Through simple modeling, it is possible to estimate the frequency of the host-guest potential and the range of the guest chromophore's angular displacement.",

author = "Sukharevsky, {Alexander P.} and Ian Read and Brian Linton and Hamilton, {Andrew D.} and Waldeck, {David H.}",

year = "1998",

month = jul,

day = "2",

language = "English (US)",

volume = "102",

pages = "5394--5403",

journal = "Journal of Physical Chemistry B",

issn = "1089-5647",

number = "27",

}

TY - JOUR

T1 - Experimental measurements of low-Frequency intermolecular host-guest dynamics

AU - Sukharevsky, Alexander P.

AU - Read, Ian

AU - Linton, Brian

AU - Hamilton, Andrew D.

AU - Waldeck, David H.

PY - 1998/7/2

Y1 - 1998/7/2

N2 - A direct temporal measurement of the internal motion of a host-guest bimolecular complex is reported. Time-resolved polarization spectroscopy is used to monitor the motion of a guest chromophore, anthracene-1,3-dicarboxylate, bound to a bis(guanidinium) host molecule through a combination of hydrogen bonding and electrostatic forces. The dynamics of the bound chromophore is well described by an overdamped oscillator model. Through simple modeling, it is possible to estimate the frequency of the host-guest potential and the range of the guest chromophore's angular displacement.

AB - A direct temporal measurement of the internal motion of a host-guest bimolecular complex is reported. Time-resolved polarization spectroscopy is used to monitor the motion of a guest chromophore, anthracene-1,3-dicarboxylate, bound to a bis(guanidinium) host molecule through a combination of hydrogen bonding and electrostatic forces. The dynamics of the bound chromophore is well described by an overdamped oscillator model. Through simple modeling, it is possible to estimate the frequency of the host-guest potential and the range of the guest chromophore's angular displacement.

UR - http://www.scopus.com/inward/record.url?scp=0007021987&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0007021987&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0007021987

SN - 1089-5647

VL - 102

SP - 5394

EP - 5403

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 27

ER -

Experimental measurements of low-Frequency intermolecular host-guest dynamics

Abstract

ASJC Scopus subject areas

Other files and links

Fingerprint

Cite this