Fiber formation by highly CO2-soluble bisureas containing peracetylated carbohydrate groups

Ik Hyeon Paik, Deepak Tapriyal, Robert M. Enick, Andrew D. Hamilton

Research output: Contribution to journalArticlepeer-review

Abstract

Like dissolves like: Bisureas containing environmentally benign CO 2-philic groups derived from peracetylated gluconic acid dissolve in supercritical CO2 at 298 K and 62 MPa. Upon depressurization of the CO2, the initially powdery bisureas (left image) form microfibrillar foams (right image). (Figure Presented).

Original languageEnglish (US)
Pages (from-to)3284-3287
Number of pages4
JournalAngewandte Chemie - International Edition
Volume46
Issue number18
DOIs
StatePublished - 2007

Keywords

  • Bisureas
  • Fibers
  • Hydrogen bonds
  • Self-assembly
  • Supercritical fluids

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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