Fluctuating Hydrodynamics and Debye-Hückel-Onsager Theory for Electrolytes

Aleksandar Donev; Alejandro L. Garcia; Jean Philippe Péraud; Andrew J. Nonaka; John B. Bell

doi:10.1016/j.coelec.2018.09.004

Fluctuating Hydrodynamics and Debye-Hückel-Onsager Theory for Electrolytes

Aleksandar Donev, Alejandro L. Garcia, Jean Philippe Péraud, Andrew J. Nonaka, John B. Bell

Mathematics

Research output: Contribution to journal › Review article › peer-review

Abstract

We apply fluctuating hydrodynamics to strong electrolyte mixtures to compute the concentration corrections for chemical potential, diffusivity, and conductivity. We show these corrections to be in agreement with the limiting laws of Debye, Hückel, and Onsager. We compute explicit corrections for a symmetric ternary mixture and find that the co-ion Maxwell-Stefan diffusion coefficients can be negative, in agreement with experimental findings.

Original language	English (US)
Pages (from-to)	1-10
Number of pages	10
Journal	Current Opinion in Electrochemistry
Volume	13
DOIs	https://doi.org/10.1016/j.coelec.2018.09.004
State	Published - Feb 2019

Keywords

Computational fluid dynamics
Electrohydrodynamics
Fluctuating hydrodynamics
Low Mach number methods
Multicomponent diffusion
Navier-Stokes equations
Nernst-Planck equations

ASJC Scopus subject areas

Analytical Chemistry
Electrochemistry

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10.1016/j.coelec.2018.09.004

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title = "Fluctuating Hydrodynamics and Debye-H{\"u}ckel-Onsager Theory for Electrolytes",

abstract = "We apply fluctuating hydrodynamics to strong electrolyte mixtures to compute the concentration corrections for chemical potential, diffusivity, and conductivity. We show these corrections to be in agreement with the limiting laws of Debye, H{\"u}ckel, and Onsager. We compute explicit corrections for a symmetric ternary mixture and find that the co-ion Maxwell-Stefan diffusion coefficients can be negative, in agreement with experimental findings.",

keywords = "Computational fluid dynamics, Electrohydrodynamics, Fluctuating hydrodynamics, Low Mach number methods, Multicomponent diffusion, Navier-Stokes equations, Nernst-Planck equations",

author = "Aleksandar Donev and Garcia, {Alejandro L.} and P{\'e}raud, {Jean Philippe} and Nonaka, {Andrew J.} and Bell, {John B.}",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",

year = "2019",

month = feb,

doi = "10.1016/j.coelec.2018.09.004",

language = "English (US)",

volume = "13",

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journal = "Current Opinion in Electrochemistry",

issn = "2451-9103",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Fluctuating Hydrodynamics and Debye-Hückel-Onsager Theory for Electrolytes

AU - Donev, Aleksandar

AU - Garcia, Alejandro L.

AU - Péraud, Jean Philippe

AU - Nonaka, Andrew J.

AU - Bell, John B.

PY - 2019/2

Y1 - 2019/2

N2 - We apply fluctuating hydrodynamics to strong electrolyte mixtures to compute the concentration corrections for chemical potential, diffusivity, and conductivity. We show these corrections to be in agreement with the limiting laws of Debye, Hückel, and Onsager. We compute explicit corrections for a symmetric ternary mixture and find that the co-ion Maxwell-Stefan diffusion coefficients can be negative, in agreement with experimental findings.

AB - We apply fluctuating hydrodynamics to strong electrolyte mixtures to compute the concentration corrections for chemical potential, diffusivity, and conductivity. We show these corrections to be in agreement with the limiting laws of Debye, Hückel, and Onsager. We compute explicit corrections for a symmetric ternary mixture and find that the co-ion Maxwell-Stefan diffusion coefficients can be negative, in agreement with experimental findings.

KW - Computational fluid dynamics

KW - Electrohydrodynamics

KW - Fluctuating hydrodynamics

KW - Low Mach number methods

KW - Multicomponent diffusion

KW - Navier-Stokes equations

KW - Nernst-Planck equations

UR - http://www.scopus.com/inward/record.url?scp=85054722668&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85054722668&partnerID=8YFLogxK

U2 - 10.1016/j.coelec.2018.09.004

DO - 10.1016/j.coelec.2018.09.004

M3 - Review article

AN - SCOPUS:85054722668

SN - 2451-9103

VL - 13

SP - 1

EP - 10

JO - Current Opinion in Electrochemistry

JF - Current Opinion in Electrochemistry

ER -

Fluctuating Hydrodynamics and Debye-Hückel-Onsager Theory for Electrolytes

Abstract

Keywords

ASJC Scopus subject areas

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