Formation of platinum nanoparticles at air-water interfaces by the spontaneous reduction of subphase chloroplatinate anions by hexadecylaniline Langmuir monolayers

Anita Swami; Ashavani Kumar; Renu Pasricha; Anandrao B. Mandale; Murali Sastry

doi:10.1016/j.jcis.2003.11.049

Formation of platinum nanoparticles at air-water interfaces by the spontaneous reduction of subphase chloroplatinate anions by hexadecylaniline Langmuir monolayers

Anita Swami, Ashavani Kumar, Renu Pasricha, Anandrao B. Mandale, Murali Sastry

Core Technology Platforms

Research output: Contribution to journal › Article › peer-review

Abstract

The one-step electrostatic complexation, reduction of aqueous chloroplatinate ions, and capping of the platinum nanoparticles thus formed by hexadecylaniline Langmuir monolayers is described. The capping of the platinum nanoparticles formed spontaneously at the air-water interface by hexadecylaniline enables their facile transfer as multilayers onto suitable solid substrates by the Langmuir-Blodgett technique. The real-time reduction of the aqueous chloroplatinate ions at the air-water interface was followed by measurement of the pressure-area isotherms, while the multilayer Langmuir-Blodgett films were characterized by quartz crystal microgravimetry, transmission electron microscopy, electron diffraction, and X-ray photoemission spectroscopy.

Original language	English (US)
Pages (from-to)	381-387
Number of pages	7
Journal	Journal of Colloid And Interface Science
Volume	271
Issue number	2
DOIs	https://doi.org/10.1016/j.jcis.2003.11.049
State	Published - Mar 15 2004

Keywords

Langmuir monolayers
Langmuir-Blodgett films
Nanoparticles
Pt
X-ray photoelectron spectroscopy

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Biomaterials
Surfaces, Coatings and Films
Colloid and Surface Chemistry

Access to Document

10.1016/j.jcis.2003.11.049

Cite this

Formation of platinum nanoparticles at air-water interfaces by the spontaneous reduction of subphase chloroplatinate anions by hexadecylaniline Langmuir monolayers. / Swami, Anita; Kumar, Ashavani; Pasricha, Renu et al.
In: Journal of Colloid And Interface Science, Vol. 271, No. 2, 15.03.2004, p. 381-387.

Research output: Contribution to journal › Article › peer-review

@article{bddeaf89f7f24c29be9642ca598ad1ca,

title = "Formation of platinum nanoparticles at air-water interfaces by the spontaneous reduction of subphase chloroplatinate anions by hexadecylaniline Langmuir monolayers",

abstract = "The one-step electrostatic complexation, reduction of aqueous chloroplatinate ions, and capping of the platinum nanoparticles thus formed by hexadecylaniline Langmuir monolayers is described. The capping of the platinum nanoparticles formed spontaneously at the air-water interface by hexadecylaniline enables their facile transfer as multilayers onto suitable solid substrates by the Langmuir-Blodgett technique. The real-time reduction of the aqueous chloroplatinate ions at the air-water interface was followed by measurement of the pressure-area isotherms, while the multilayer Langmuir-Blodgett films were characterized by quartz crystal microgravimetry, transmission electron microscopy, electron diffraction, and X-ray photoemission spectroscopy.",

keywords = "Langmuir monolayers, Langmuir-Blodgett films, Nanoparticles, Pt, X-ray photoelectron spectroscopy",

author = "Anita Swami and Ashavani Kumar and Renu Pasricha and Mandale, {Anandrao B.} and Murali Sastry",

note = "Funding Information: A.S. and A.K. thank the Council for Scientific and Industrial Research (CSIR), Government of India, for research fellowships. This work was partially funded by a grant from the Department of Science and Technology (DST), Government of India, which is gratefully acknowledged. Copyright: Copyright 2017 Elsevier B.V., All rights reserved.",

year = "2004",

month = mar,

day = "15",

doi = "10.1016/j.jcis.2003.11.049",

language = "English (US)",

volume = "271",

pages = "381--387",

journal = "Journal of Colloid And Interface Science",

issn = "0021-9797",

publisher = "Academic Press Inc.",

number = "2",

}

TY - JOUR

T1 - Formation of platinum nanoparticles at air-water interfaces by the spontaneous reduction of subphase chloroplatinate anions by hexadecylaniline Langmuir monolayers

AU - Swami, Anita

AU - Kumar, Ashavani

AU - Pasricha, Renu

AU - Mandale, Anandrao B.

AU - Sastry, Murali

N1 - Funding Information: A.S. and A.K. thank the Council for Scientific and Industrial Research (CSIR), Government of India, for research fellowships. This work was partially funded by a grant from the Department of Science and Technology (DST), Government of India, which is gratefully acknowledged. Copyright: Copyright 2017 Elsevier B.V., All rights reserved.

PY - 2004/3/15

Y1 - 2004/3/15

N2 - The one-step electrostatic complexation, reduction of aqueous chloroplatinate ions, and capping of the platinum nanoparticles thus formed by hexadecylaniline Langmuir monolayers is described. The capping of the platinum nanoparticles formed spontaneously at the air-water interface by hexadecylaniline enables their facile transfer as multilayers onto suitable solid substrates by the Langmuir-Blodgett technique. The real-time reduction of the aqueous chloroplatinate ions at the air-water interface was followed by measurement of the pressure-area isotherms, while the multilayer Langmuir-Blodgett films were characterized by quartz crystal microgravimetry, transmission electron microscopy, electron diffraction, and X-ray photoemission spectroscopy.

AB - The one-step electrostatic complexation, reduction of aqueous chloroplatinate ions, and capping of the platinum nanoparticles thus formed by hexadecylaniline Langmuir monolayers is described. The capping of the platinum nanoparticles formed spontaneously at the air-water interface by hexadecylaniline enables their facile transfer as multilayers onto suitable solid substrates by the Langmuir-Blodgett technique. The real-time reduction of the aqueous chloroplatinate ions at the air-water interface was followed by measurement of the pressure-area isotherms, while the multilayer Langmuir-Blodgett films were characterized by quartz crystal microgravimetry, transmission electron microscopy, electron diffraction, and X-ray photoemission spectroscopy.

KW - Langmuir monolayers

KW - Langmuir-Blodgett films

KW - Nanoparticles

KW - Pt

KW - X-ray photoelectron spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=1242270492&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=1242270492&partnerID=8YFLogxK

U2 - 10.1016/j.jcis.2003.11.049

DO - 10.1016/j.jcis.2003.11.049

M3 - Article

C2 - 14972616

AN - SCOPUS:1242270492

SN - 0021-9797

VL - 271

SP - 381

EP - 387

JO - Journal of Colloid And Interface Science

JF - Journal of Colloid And Interface Science

IS - 2

ER -

Formation of platinum nanoparticles at air-water interfaces by the spontaneous reduction of subphase chloroplatinate anions by hexadecylaniline Langmuir monolayers

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this