Abstract
A number of techniques are presented for extrapolating from knowledge of the direct correlation function for a uniform fluid at various densities to that of the free energy and associated density profile of a nonuniform fluid. A primitive mathematical model is followed by models based upon physical characteristics of exactly solved systems, from the nonnegativity of linear response functions to the explicit form of a nonuniform hard rod fluid. Attention is paid to physical requirements which are not satisfied and suggestions are made for future progress.
Original language | English (US) |
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Pages (from-to) | 1157-1178 |
Number of pages | 22 |
Journal | Journal of Statistical Physics |
Volume | 52 |
Issue number | 5-6 |
DOIs | |
State | Published - Sep 1988 |
Keywords
- Nonuniform fluid
- density functional
- positivity restrictions
- profile equation
ASJC Scopus subject areas
- Statistical and Nonlinear Physics
- Mathematical Physics