From nuclear structure to the quadrupolar NMR interaction and high-resolution spectroscopy

Research output: Contribution to journalReview articlepeer-review

Abstract

The relation of nuclear physics with quadrupolar NMR interaction and high-resolution spectroscopy is discussed. The nuclear structure and spin, nucleus-electron interaction, quantum nucleus-electron interaction and the ionic model for electric field gradients, Sternheimer factor are also discussed. The appearance of spectra under the action of the quarupolar NMR Hamiltonian which include, first- and second-order effects, the nuclear quadrupole resonance, and cross-terms with the dipolar and chemical shift anisotropy interactions, are also discussed. The high-resolution techniques such as, double rotation, dynamic-angle spinning, multiple-quantum magic-angle spinning, and satellite transition magic-angle spinning.

Original languageEnglish (US)
Pages (from-to)63-78
Number of pages16
JournalProgress in Nuclear Magnetic Resonance Spectroscopy
Volume46
Issue number1
DOIs
StatePublished - Mar 17 2005

Keywords

  • DAS
  • DOR
  • Electric field gradient
  • MQMAS
  • NQR
  • Nuclear quadrupole moment
  • Nuclear structure and spin
  • Quadrupolar coupling
  • STMAS
  • Solid-state NMR

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Nuclear and High Energy Physics
  • Spectroscopy

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