TY - JOUR
T1 - From nuclear structure to the quadrupolar NMR interaction and high-resolution spectroscopy
AU - Jerschow, Alexej
N1 - Funding Information:
The author wishes to express his gratitude for very insightful and stimulating discussions with S. Vega, C.P. Slichter, S. Wimperis, P.K. Madhu, G. Denninger, and S.C. Shekar. This work also benefitted from infrastructure provided through a National Science Foundation Grant, ‘Research Coordination Network for NMR of Biological Solids’ (MCB-0233854). The author is a member of the New York Structural Biology Center supported by NIH Grant 1P41GM66354 and the Center's Metagroup Meetings are acknowledged for helpful discussions.
PY - 2005/3/17
Y1 - 2005/3/17
N2 - The relation of nuclear physics with quadrupolar NMR interaction and high-resolution spectroscopy is discussed. The nuclear structure and spin, nucleus-electron interaction, quantum nucleus-electron interaction and the ionic model for electric field gradients, Sternheimer factor are also discussed. The appearance of spectra under the action of the quarupolar NMR Hamiltonian which include, first- and second-order effects, the nuclear quadrupole resonance, and cross-terms with the dipolar and chemical shift anisotropy interactions, are also discussed. The high-resolution techniques such as, double rotation, dynamic-angle spinning, multiple-quantum magic-angle spinning, and satellite transition magic-angle spinning.
AB - The relation of nuclear physics with quadrupolar NMR interaction and high-resolution spectroscopy is discussed. The nuclear structure and spin, nucleus-electron interaction, quantum nucleus-electron interaction and the ionic model for electric field gradients, Sternheimer factor are also discussed. The appearance of spectra under the action of the quarupolar NMR Hamiltonian which include, first- and second-order effects, the nuclear quadrupole resonance, and cross-terms with the dipolar and chemical shift anisotropy interactions, are also discussed. The high-resolution techniques such as, double rotation, dynamic-angle spinning, multiple-quantum magic-angle spinning, and satellite transition magic-angle spinning.
KW - DAS
KW - DOR
KW - Electric field gradient
KW - MQMAS
KW - NQR
KW - Nuclear quadrupole moment
KW - Nuclear structure and spin
KW - Quadrupolar coupling
KW - STMAS
KW - Solid-state NMR
UR - http://www.scopus.com/inward/record.url?scp=14844346807&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=14844346807&partnerID=8YFLogxK
U2 - 10.1016/j.pnmrs.2004.12.001
DO - 10.1016/j.pnmrs.2004.12.001
M3 - Review article
AN - SCOPUS:14844346807
SN - 0079-6565
VL - 46
SP - 63
EP - 78
JO - Progress in Nuclear Magnetic Resonance Spectroscopy
JF - Progress in Nuclear Magnetic Resonance Spectroscopy
IS - 1
ER -