TY - JOUR
T1 - FT infrared spectra of binuclear copper(II) imidazole saccharinato complex
T2 - Correlation with the structure
AU - Naumov, Panče
AU - Jovanovski, Gligor
N1 - Funding Information:
The authors thank Dr Orhideja GrupEe for recording the far infrared spectrum as well as for her interest for this work, The financial support from the Ministry for Science of the Republic of Macedonia is gratefully acknowledged.
PY - 1999
Y1 - 1999
N2 - The FT infrared spectra of the binuclear copper(II) complex with imidazole and saccharin and of its iminodeuterated analogue at room (RT) and liquid nitrogen temperature (LNT) are recorded. The bands that are mainly due to the NH, ND, CO, SO2 and metal-ligand stretchings are assigned. The spectral characteristics are correlated with the available structural data and compared with the corresponding data for other saccharinates and imidazole complexes. While the spectral appearance in the NH, ND and SO2 regions is in agreement with the structural data, the carbonyl stretchings do not conform the pronounced difference between the lengths of the two structurally non-equivalent carbonyl groups found by earlier structural studies.
AB - The FT infrared spectra of the binuclear copper(II) complex with imidazole and saccharin and of its iminodeuterated analogue at room (RT) and liquid nitrogen temperature (LNT) are recorded. The bands that are mainly due to the NH, ND, CO, SO2 and metal-ligand stretchings are assigned. The spectral characteristics are correlated with the available structural data and compared with the corresponding data for other saccharinates and imidazole complexes. While the spectral appearance in the NH, ND and SO2 regions is in agreement with the structural data, the carbonyl stretchings do not conform the pronounced difference between the lengths of the two structurally non-equivalent carbonyl groups found by earlier structural studies.
KW - Copper imidazole saccharinate
KW - FT IR spectra
KW - Spectra-structure correlations
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U2 - 10.1080/00387019909349980
DO - 10.1080/00387019909349980
M3 - Article
AN - SCOPUS:0000022050
SN - 0038-7010
VL - 32
SP - 237
EP - 256
JO - Spectroscopy Letters
JF - Spectroscopy Letters
IS - 2
ER -