Heavy-atom skeleton quantization and proton tunneling in "intermediate-barrier" hydrogen bonds

Mark E. Tuckerman; Dominik Marx

doi:10.1103/PhysRevLett.86.4946

Heavy-atom skeleton quantization and proton tunneling in "intermediate-barrier" hydrogen bonds

Mark E. Tuckerman, Dominik Marx

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The problem of heavy atom quantization was studied using malonaldehyde in the gas phase at room temperature as a prototypical example of intermediate-barrier proton transfer. Quantum effects on proton transfer were clarified. Proton tunneling was enhanced by the quantum nature of the heavy molecular frame atoms.

Original language	English (US)
Pages (from-to)	4946-4949
Number of pages	4
Journal	Physical Review Letters
Volume	86
Issue number	21
DOIs	https://doi.org/10.1103/PhysRevLett.86.4946
State	Published - May 21 2001

ASJC Scopus subject areas

General Physics and Astronomy

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10.1103/PhysRevLett.86.4946

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abstract = "The problem of heavy atom quantization was studied using malonaldehyde in the gas phase at room temperature as a prototypical example of intermediate-barrier proton transfer. Quantum effects on proton transfer were clarified. Proton tunneling was enhanced by the quantum nature of the heavy molecular frame atoms.",

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Heavy-atom skeleton quantization and proton tunneling in "intermediate-barrier" hydrogen bonds

Abstract

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