Hydroperoxidations of Alkenes using Cobalt Picolinate Catalysts

Zulema Peralta-Neel; K. A. Woerpel

doi:10.1021/acs.orglett.1c01489

Hydroperoxidations of Alkenes using Cobalt Picolinate Catalysts

Zulema Peralta-Neel, K. A. Woerpel

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Hydroperoxides were synthesized in one step from various alkenes using Co(pic)₂as the catalyst with molecular oxygen and tetramethyldisiloxane (TMDSO). The hydration product could be obtained using a modified catalyst, Co(3-mepic)₂, with molecular oxygen and phenylsilane. Formation of hydroperoxides occurred through a rapid Co-O bond metathesis of a peroxycobalt compound with isopropanol.

Original language	English (US)
Pages (from-to)	5002-5006
Number of pages	5
Journal	Organic Letters
Volume	23
Issue number	13
DOIs	https://doi.org/10.1021/acs.orglett.1c01489
State	Published - Jul 2 2021

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.1021/acs.orglett.1c01489

Cite this

@article{32b5bb47ae574705a3b5c446ab4090ab,

title = "Hydroperoxidations of Alkenes using Cobalt Picolinate Catalysts",

abstract = "Hydroperoxides were synthesized in one step from various alkenes using Co(pic)2as the catalyst with molecular oxygen and tetramethyldisiloxane (TMDSO). The hydration product could be obtained using a modified catalyst, Co(3-mepic)2, with molecular oxygen and phenylsilane. Formation of hydroperoxides occurred through a rapid Co-O bond metathesis of a peroxycobalt compound with isopropanol.",

author = "Zulema Peralta-Neel and Woerpel, {K. A.}",

note = "Publisher Copyright: {\textcopyright} 2021 American Chemical Society",

year = "2021",

month = jul,

day = "2",

doi = "10.1021/acs.orglett.1c01489",

language = "English (US)",

volume = "23",

pages = "5002--5006",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "13",

}

TY - JOUR

T1 - Hydroperoxidations of Alkenes using Cobalt Picolinate Catalysts

AU - Peralta-Neel, Zulema

AU - Woerpel, K. A.

PY - 2021/7/2

Y1 - 2021/7/2

N2 - Hydroperoxides were synthesized in one step from various alkenes using Co(pic)2as the catalyst with molecular oxygen and tetramethyldisiloxane (TMDSO). The hydration product could be obtained using a modified catalyst, Co(3-mepic)2, with molecular oxygen and phenylsilane. Formation of hydroperoxides occurred through a rapid Co-O bond metathesis of a peroxycobalt compound with isopropanol.

AB - Hydroperoxides were synthesized in one step from various alkenes using Co(pic)2as the catalyst with molecular oxygen and tetramethyldisiloxane (TMDSO). The hydration product could be obtained using a modified catalyst, Co(3-mepic)2, with molecular oxygen and phenylsilane. Formation of hydroperoxides occurred through a rapid Co-O bond metathesis of a peroxycobalt compound with isopropanol.

UR - http://www.scopus.com/inward/record.url?scp=85108584340&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85108584340&partnerID=8YFLogxK

U2 - 10.1021/acs.orglett.1c01489

DO - 10.1021/acs.orglett.1c01489

M3 - Article

C2 - 34125543

AN - SCOPUS:85108584340

SN - 1523-7060

VL - 23

SP - 5002

EP - 5006

JO - Organic Letters

JF - Organic Letters

IS - 13

ER -

Hydroperoxidations of Alkenes using Cobalt Picolinate Catalysts

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this