Influence of perfluoroarene - Arene interactions on the phase behavior of liquid crystalline and polymeric materials

Marcus Weck; Alex R. Dunn; Kozo Matsumoto; Geoffrey W. Coates; Emil B. Lobkovsky; Robert H. Grubbs

doi:10.1002/(SICI)1521-3773(19990917)38:18<2741::AID-ANIE2741>3.0.CO;2-1

Influence of perfluoroarene - Arene interactions on the phase behavior of liquid crystalline and polymeric materials

Marcus Weck, Alex R. Dunn, Kozo Matsumoto, Geoffrey W. Coates, Emil B. Lobkovsky, Robert H. Grubbs

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A stabilization of the liquid-crystalline mesophase and thus an enlarged temperature range of the mesogenic phase is achieved by adding perfluorotriphenylene to a chiral liquid-crystalline triphenylene. This mesophase is based on 1:1 perfluoroarene-arene interactions (see picture). In a polymer with triphenylenes as mesogens in the side chains, the addition of perfluorotriphenylene led to crystallization.

Original language	English (US)
Pages (from-to)	2741-2745
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	38
Issue number	18
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19990917)38:18<2741::AID-ANIE2741>3.0.CO;2-1
State	Published - Sep 17 1999

Keywords

Arenes
Liquid crystals
Polymerizations
Stacking interactions
Supramolecular chemistry

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/(SICI)1521-3773(19990917)38:18<2741::AID-ANIE2741>3.0.CO;2-1

Cite this

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abstract = "A stabilization of the liquid-crystalline mesophase and thus an enlarged temperature range of the mesogenic phase is achieved by adding perfluorotriphenylene to a chiral liquid-crystalline triphenylene. This mesophase is based on 1:1 perfluoroarene-arene interactions (see picture). In a polymer with triphenylenes as mesogens in the side chains, the addition of perfluorotriphenylene led to crystallization.",

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T1 - Influence of perfluoroarene - Arene interactions on the phase behavior of liquid crystalline and polymeric materials

AU - Weck, Marcus

AU - Dunn, Alex R.

AU - Matsumoto, Kozo

AU - Coates, Geoffrey W.

AU - Lobkovsky, Emil B.

AU - Grubbs, Robert H.

PY - 1999/9/17

Y1 - 1999/9/17

N2 - A stabilization of the liquid-crystalline mesophase and thus an enlarged temperature range of the mesogenic phase is achieved by adding perfluorotriphenylene to a chiral liquid-crystalline triphenylene. This mesophase is based on 1:1 perfluoroarene-arene interactions (see picture). In a polymer with triphenylenes as mesogens in the side chains, the addition of perfluorotriphenylene led to crystallization.

AB - A stabilization of the liquid-crystalline mesophase and thus an enlarged temperature range of the mesogenic phase is achieved by adding perfluorotriphenylene to a chiral liquid-crystalline triphenylene. This mesophase is based on 1:1 perfluoroarene-arene interactions (see picture). In a polymer with triphenylenes as mesogens in the side chains, the addition of perfluorotriphenylene led to crystallization.

KW - Arenes

KW - Liquid crystals

KW - Polymerizations

KW - Stacking interactions

KW - Supramolecular chemistry

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Influence of perfluoroarene - Arene interactions on the phase behavior of liquid crystalline and polymeric materials

Abstract

Keywords

ASJC Scopus subject areas

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