Infrared hole burning and conformational change in a borane - Ammonia complex

Christopher A. Endicott; Herbert L. Strauss; Chambers C. Hughes; Dirk Trauner

doi:10.1021/jp051969i

Infrared hole burning and conformational change in a borane - Ammonia complex

Christopher A. Endicott, Herbert L. Strauss, Chambers C. Hughes, Dirk Trauner

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The N-D stretching region in the infrared spectrum of the ammonia complex of tris-(2-methoxymethylphenol)-borane containing one D atom has been examined. The N-D bands have been hole burned, and the resulting spectra reveal the reorientation kinetics of the ammonia. The ammonia is hydrogen bonded with the bond distances and reorientation barrier typical of other compounds. The N-D stretching frequencies are higher than those of comparison compounds.

Original language	English (US)
Pages (from-to)	7714-7717
Number of pages	4
Journal	Journal of Physical Chemistry A
Volume	109
Issue number	34
DOIs	https://doi.org/10.1021/jp051969i
State	Published - Sep 1 2005

ASJC Scopus subject areas

Physical and Theoretical Chemistry

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abstract = "The N-D stretching region in the infrared spectrum of the ammonia complex of tris-(2-methoxymethylphenol)-borane containing one D atom has been examined. The N-D bands have been hole burned, and the resulting spectra reveal the reorientation kinetics of the ammonia. The ammonia is hydrogen bonded with the bond distances and reorientation barrier typical of other compounds. The N-D stretching frequencies are higher than those of comparison compounds.",

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N2 - The N-D stretching region in the infrared spectrum of the ammonia complex of tris-(2-methoxymethylphenol)-borane containing one D atom has been examined. The N-D bands have been hole burned, and the resulting spectra reveal the reorientation kinetics of the ammonia. The ammonia is hydrogen bonded with the bond distances and reorientation barrier typical of other compounds. The N-D stretching frequencies are higher than those of comparison compounds.

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Infrared hole burning and conformational change in a borane - Ammonia complex

Abstract

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