(Chemical Equation Presented) Silacarbonyl ylides, generated by metal-catalyzed silylene transfer to carbonyls, participate in formal intermolecular 1,3-dipolar cycloaddition reactions with carbonyl compounds and alkynes to form dioxasilacyclopentane acetals and oxasilacyclopentenes in an efficient, one-step process.
|Original language||English (US)|
|Number of pages||4|
|State||Published - 2008|
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry