Intermolecular silacarbonyl ylide cycloadditions: A direct pathway to oxasilacyclopentenes

Laura E. Bourque; K. A. Woerpel

doi:10.1021/ol8018538

Intermolecular silacarbonyl ylide cycloadditions: A direct pathway to oxasilacyclopentenes

Laura E. Bourque, K. A. Woerpel

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

(Chemical Equation Presented) Silacarbonyl ylides, generated by metal-catalyzed silylene transfer to carbonyls, participate in formal intermolecular 1,3-dipolar cycloaddition reactions with carbonyl compounds and alkynes to form dioxasilacyclopentane acetals and oxasilacyclopentenes in an efficient, one-step process.

Original language	English (US)
Pages (from-to)	5257-5260
Number of pages	4
Journal	Organic Letters
Volume	10
Issue number	22
DOIs	https://doi.org/10.1021/ol8018538
State	Published - 2008

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol8018538

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title = "Intermolecular silacarbonyl ylide cycloadditions: A direct pathway to oxasilacyclopentenes",

abstract = "(Chemical Equation Presented) Silacarbonyl ylides, generated by metal-catalyzed silylene transfer to carbonyls, participate in formal intermolecular 1,3-dipolar cycloaddition reactions with carbonyl compounds and alkynes to form dioxasilacyclopentane acetals and oxasilacyclopentenes in an efficient, one-step process.",

author = "Bourque, {Laura E.} and Woerpel, {K. A.}",

year = "2008",

doi = "10.1021/ol8018538",

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publisher = "American Chemical Society",

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T1 - Intermolecular silacarbonyl ylide cycloadditions

T2 - A direct pathway to oxasilacyclopentenes

AU - Bourque, Laura E.

AU - Woerpel, K. A.

PY - 2008

Y1 - 2008

N2 - (Chemical Equation Presented) Silacarbonyl ylides, generated by metal-catalyzed silylene transfer to carbonyls, participate in formal intermolecular 1,3-dipolar cycloaddition reactions with carbonyl compounds and alkynes to form dioxasilacyclopentane acetals and oxasilacyclopentenes in an efficient, one-step process.

AB - (Chemical Equation Presented) Silacarbonyl ylides, generated by metal-catalyzed silylene transfer to carbonyls, participate in formal intermolecular 1,3-dipolar cycloaddition reactions with carbonyl compounds and alkynes to form dioxasilacyclopentane acetals and oxasilacyclopentenes in an efficient, one-step process.

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JO - Organic Letters

JF - Organic Letters

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Intermolecular silacarbonyl ylide cycloadditions: A direct pathway to oxasilacyclopentenes

Abstract

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