Intramolecular folding of triblock copolymers via quadrupole interactions between poly(styrene) and poly(pentafluorostyrene) blocks

Jie Lu; Niels N. Ten Brummelhuis; Marcus Weck

doi:10.1039/c4cc01840k

Intramolecular folding of triblock copolymers via quadrupole interactions between poly(styrene) and poly(pentafluorostyrene) blocks

Jie Lu, Niels N. Ten Brummelhuis, Marcus Weck

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

β-Hairpin formation is one of the fundamental folding actions in biomacromolecules. We present a linear triblock copolymer synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization, that is able to mimic on a very basic level hairpin formation by using π-π stacking interactions between phenyl and 2,3,4,5,6-pentafluorophenyl residues.

Original language	English (US)
Pages (from-to)	6225-6227
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	47
DOIs	https://doi.org/10.1039/c4cc01840k
State	Published - May 16 2014

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "β-Hairpin formation is one of the fundamental folding actions in biomacromolecules. We present a linear triblock copolymer synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization, that is able to mimic on a very basic level hairpin formation by using π-π stacking interactions between phenyl and 2,3,4,5,6-pentafluorophenyl residues.",

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PY - 2014/5/16

Y1 - 2014/5/16

N2 - β-Hairpin formation is one of the fundamental folding actions in biomacromolecules. We present a linear triblock copolymer synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization, that is able to mimic on a very basic level hairpin formation by using π-π stacking interactions between phenyl and 2,3,4,5,6-pentafluorophenyl residues.

AB - β-Hairpin formation is one of the fundamental folding actions in biomacromolecules. We present a linear triblock copolymer synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization, that is able to mimic on a very basic level hairpin formation by using π-π stacking interactions between phenyl and 2,3,4,5,6-pentafluorophenyl residues.

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Intramolecular folding of triblock copolymers via quadrupole interactions between poly(styrene) and poly(pentafluorostyrene) blocks

Abstract

ASJC Scopus subject areas

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