Intramolecular redox-induced dimerization in a viologen dendrimer

Kuldeep Wadhwa, Selbi Nuryyeva, Albert C. Fahrenbach, Mourad Elhabiri, Carlos Platas-Iglesias, Ali Trabolsi

Research output: Contribution to journalArticlepeer-review

Abstract

The redox chemistry of a newly synthesized small dendrimer containing six peripheral viologen units and a phosphazene core is described. The one-electron reduction of each viologen (total six electrons) leads to intermolecular dimerization of the reduced viologens borne by the same phosphorous atom, resulting in a color change from colourless to purple providing it with potential electrochromic applications.

Original languageEnglish (US)
Pages (from-to)2302-2307
Number of pages6
JournalJournal of Materials Chemistry C
Volume1
Issue number12
DOIs
StatePublished - Mar 28 2013

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry

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