Investigations into the role of ion pairing in reactions of heteroatom-substituted cyclic oxocarbenium ions

Siddhartha R. Shenoy; K. A. Woerpel

doi:10.1021/ol0500620

Investigations into the role of ion pairing in reactions of heteroatom-substituted cyclic oxocarbenium ions

Siddhartha R. Shenoy, K. A. Woerpel

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

(Chemical Equation Presented) The O-to-C rearrangement of vinyl acetals is used to demonstrate that tight ion pairing is not involved in the stereoselective nucleophilic addition reactions of alkoxy-substituted cyclic oxocarbenium ions.

Original language	English (US)
Pages (from-to)	1157-1160
Number of pages	4
Journal	Organic Letters
Volume	7
Issue number	6
DOIs	https://doi.org/10.1021/ol0500620
State	Published - Mar 17 2005

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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title = "Investigations into the role of ion pairing in reactions of heteroatom-substituted cyclic oxocarbenium ions",

abstract = "(Chemical Equation Presented) The O-to-C rearrangement of vinyl acetals is used to demonstrate that tight ion pairing is not involved in the stereoselective nucleophilic addition reactions of alkoxy-substituted cyclic oxocarbenium ions.",

author = "Shenoy, {Siddhartha R.} and Woerpel, {K. A.}",

year = "2005",

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doi = "10.1021/ol0500620",

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journal = "Organic Letters",

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Y1 - 2005/3/17

N2 - (Chemical Equation Presented) The O-to-C rearrangement of vinyl acetals is used to demonstrate that tight ion pairing is not involved in the stereoselective nucleophilic addition reactions of alkoxy-substituted cyclic oxocarbenium ions.

AB - (Chemical Equation Presented) The O-to-C rearrangement of vinyl acetals is used to demonstrate that tight ion pairing is not involved in the stereoselective nucleophilic addition reactions of alkoxy-substituted cyclic oxocarbenium ions.

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Investigations into the role of ion pairing in reactions of heteroatom-substituted cyclic oxocarbenium ions

Abstract

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